Category Archives: Liquid Biofuels: Emergence, Development and

Environmental Impacts of Biofuels: The GHG Emissions Saving

One of the aims for the utilization of biofuels is the climate change mitigation through the reduction of GHG emissions in the transport sector. Measuring the con­sequences of biofuels requires consideration of their full life cycle, from biomass pro­duction and its use of various inputs to the conversion of feedstocks into liquid fuels and the subsequent use of the biofuels in combustion engines (Rasetti et al. 2012).

The potential mitigation varies across types of feedstock, feedstock production process/technology (e. g., usage of nitrogen fertilizer), and fossil fuel consumption in both production of feedstocks and its conversion to biofuels.

Several standard life cycle analyses (LCA) of biofuels in the literature have reported a wide variation on the reduction of GHG emissions; this is mainly due to differences on underlying assumptions on system boundaries, by-product alloca­tion, and energy sources used in the production of agricultural inputs and feedstock conversion to biofuels. Most studies (Sims et al. 2010; Rutz and Janssen 2007) indicate that biofuels show some emission reductions when compared to their fossil fuel counterparts, especially when the emissions from the director indirect land-use changes (LUC/ILUC) due to biofuels feedstock production are excluded.

PNPB: Social Arrangements Undertaken Regarding Palm Oil

According to the respondents consulted in this study, the social projects related to PNPB’s palm oil production are considered pilot studies. To date, these have been implemented by a single company. The Agropalma Group operates in agribusi­ness since 1982 and is the largest and most modern agro-industrial palm produc­tion and palm oil processing complex in the country. In order to assess the family farmers’ insertion difficulties, a description of the social organization of palm, the Agropalma unit in the municipality of Tailandia in the interior of Para was visited. This unit is located 343 km from Belem (Fig. 1).

Overall, a total of 185 families have been integrated into the company, all with an average area of 10 ha according to PNPB’s organization models with partner­ship contracts. In the projects presented by Brito (2010), 10-ha lots (indicated by the shaded area in Fig. 2) were distributed to the first 150 families. This enabled to better organize and concentrate the palm oil plantation. These families (former “squatters”) were relocated in the region and received government lots of up to 50 ha for other crops. However, in the plantations within the INCRA settlements, the palm oil plantation is more dispersed, conducted within the boundaries of the property previously distributed by the institute, which occupies somewhat smaller areas (about 6 ha) than the pioneering projects.

According to the representatives, the company provides technical assistance (at a symbolic price), seedlings, and fertilizers (at market prices, i. e., negotiated with other inputs purchased for of the company’s scale operation) to the family farmers. The values are repassed to the farmer and payment remittance is made in 25 years, term agreement of the clusters provided by the farmers to the processing industry. To encourage the fam­ily farmer’s commitment to the production system, the company created a program to pay for the quality of the cluster. In addition, the company pays a surcharge, which can be up to 8 %, according to the quality observed upon delivery of the raw material.

The bank gives a loan related to implement the crop by the farmer and the loan related to the monthly sum paid to the farmer family during the crop formation period. The 3-year period is considered critical to the sum paid to the farmer fam­ily success of the venture

After the first year of production, which is the third year after the crops are planted, 25 % of the cluster production sales are retained, which is destined to repay the debts to the company. Afterward, it deposits the remaining amount into the farm­er’s bank account. The bank, in turn, also retains 25 % to pay for the debt it acquired. In all, 50 % of the family’s income is retained, and these gains vary according to the growth stage of the crop, which is estimated to be of around US$67,300 (Fig. 3).

As for palm oil, there is a high risk involved for a loan around US$3,000,000 to plant 10 ha of oil palm (fostered family farming model area until the present time). By retaining the loan payment by the bank itself, the system imposes the debt repayment. As the company is a type of guarantor, when it invests its own recourses in the arrange­ment, it is then considered a partner in the business, which at this stage is advantageous to the farmer given the difficulties involved in this high investment process.

To encourage the family farmers’ involvement in the production system, the company set up a payment program according to the quality of the fruit bunch. Bonus payment is only done if the production and management controls of the land are up to date with the guidance provided by the technicians.

In general, the consensus is that oil palm has provided a significant income increase to the family farmers involved in the program. Before the project, farm­ers practically lived on the income from cassava flour, which was used as currency to purchase other foods (salt, sugar, and so forth) brought in small vessels and sold by middlemen. According to the farmers interviewed, back then the monthly income varied from US$2,250 to 4,500.

With regard to oil palm, the representatives of the only company that actually has effective arrangements with palm growers claim that they are not favored with the tax benefits of the seal, due to the fact that the projects signed are considered pilot projects and also because of the small volume of biodiesel produced. Thus, for this company, this new venture is still considered peripheral and in the testing phase. However, it is likely that biodiesel companies entering this sector may also face several difficulties, given that in practice, there is a higher cost to implement projects with family farmers in deprived areas with difficult access, especially in regions lacking cooperative and large-scale production tradition—which is the case in the main regions that cultivate oil palm. This survey is deeply exposed at Cesar and Batalha (2013).

Technical Barriers to Advanced Liquid Biofuels Production via Biochemical Route

Biswarup Sen

Abstract In the past decades, the ‘food versus fuel’ debate has caused a transition of first-generation biofuels to advanced biofuels. Although the later seems quite promising, due to its sustainability and low GHG emissions qualities, it is still far from deployment. The major hurdles to the deployment of advanced biofuels include technical and economic challenges, which must be overcome in the near future. Extensive R&D is in progress to bridge the gap between the current techno­logical status and commercial venture. To overcome the significant challenges that make the commercialization of advanced liquid biofuels unrealistic, at this moment, is of prime importance. One of the most significant challenges is the technological barriers, which will probably require some more years of extensive R&D efforts to minimize the issues and concerns. This chapter deals with the technological challenges that the liquid biofuels industry is currently facing in the biochemical conversion of second- and third-generation feedstocks to advanced liquid biofuels. A general introduction to the topic includes the types of liquid biofuels categorized under ‘advanced biofuels’ and their common routes of production namely biochem­ical and thermochemical. A detailed description of the current technological issues in the biochemical conversion process is presented mainly under the subcategories: improving feedstocks, pretreatment methods, hydrolytic enzymes efficacy and cost, and process integration. The chapter ends with a review of the current status of R&D in biochemical conversion route for advanced liquid biofuels.

B. Sen (*)

Department of Environment Engineering and Science, Feng Chia University,

Taichung 40724, Taiwan

e-mail: bsen@fcu. edu. tw; bisens@yahoo. com

B. Sen

Master Program of Green Energy Science and Technology, Feng Chia University, Taichung 40724, Taiwan

B. Sen

Green Energy Development Center, Feng Chia University, Taichung 40724, Taiwan

A. Domingos Padula et al. (eds.), Liquid Biofuels: Emergence, Development and Prospects, Lecture Notes in Energy 27, DOI: 10.1007/978-1-4471-6482-1_10, © Springer-Verlag London 2014

1 Introduction

Biofuels can be produced from agricultural or industrial wastes and are renewable with a potential to decrease our society’s dependence on petroleum. Focus on bio­fuels has gained global attention both amidst the general mass and scientific com­munity, due to various compelling factors such as increasing oil prices, low carbon emission of biofuels, and less impact on the environment. Among all biofuels, liq­uid biofuels have attracted attention of the scientific community, as it is the most convenient form of fuel for the automobile industry. Liquid biofuels usually include bioethanol, biodiesel, butanol, and oil from algae (Demirbas 2009). Bioethanol is produced by fermentation of sugars (carbohydrates) usually derived from sugar — rich crops like sugarcane or sugar beet and/or from starch-rich crops like corn (first-generation biofuel). Bioethanol is also produced from cellulosic biomass (non-food sources) and from grasses and trees (second generation). Bioethanol is widely used in Brazil and also in the USA.

Biodiesel, on the other hand, is produced by trans-esterification of oils, and its chemical composition consists of fatty acid methyl esters (FAMEs). Feedstocks from which biodiesel is produced usually include animal fats, vegetable oils, palm oil, soy, jatropha, mustard, flax, sunflower, pongamia, and algae. Biodiesel can be used in blends with petrodiesel, the purest form of which is B100; however, B20 and lower blends are suitable for diesel engines. Recently, biobutanol production is being researched extensively owing to its better properties as a fuel than bioethanol and is usually produced under anaerobic fermentation called ABE (acetone, butanol, and ethanol) fermentation. Starch can be fermented by microorganisms like Clostridium to produce ABE in the ratio of 3:6:1. Ralstonia sp. can be used to produce biobu­tanol in electro-bioreactor using carbon dioxide and electricity. Metabolically engi­neered E. coli have also been shown to produce butanol. DuPont and BP have jointly ventured into the large-scale production of butanol (Anton and Dobson 2008).

Worldwide biofuel production has reached 105 billion liters in 2010, up by 17 % from 2009; still biofuels just fulfill 2.7 % of the world’s fuel need for transporta­tion. Brazil and USA are currently top producers, accounting for 90 % of total global production of biofuels, while biodiesel production by the EU accounts for 53 % of total biodiesel production as of 2010. The International Energy Agency (IEA) has a mission for biofuels in meeting the demand for global fuel production at least by a quarter by 2050. Global ethanol production for use as bioethanol tripled between the period 2000 and 2007, which amounts to 52 billion liters. In recent years (2011), its production reached 84.6 billion liters; the USA topped with 52.6 billion lit­ers ethanol production, contributing 62.2 % in global production, whereas Brazil with 21.1 billion liters ranked second. Ethanol-based fuel is largely used in Brazil and in the USA, responsible for 87.1 % global ethanol-based fuel production as of 2011. Most cars in the USA run on blends of up to 10 % ethanol. Brazilian gov­ernment has made it mandatory since 1976 to blend ethanol with gasoline; from 2007 onwards, the legal blend is E25. As of December 2011, Brazil had 14.8 mil­lion automobiles and 1.5 million motorcycles that use only pure ethanol fuel (E100).

The USA uses com as a major source to produce bioethanol. Com in general is an energy-intensive crop, consuming a unit of fossil-based fuel energy to create just 0.9-1.3 energy units of bioethanol. General Motors has initiated production of E85 fuel from cellulose ethanol for a possible projected cost of $1 a gallon.

A directive issued in 2010 by the EU has a targeted goal where all members are required to achieve a 5-10 % biofuel usage by 2020. India and China are vastly exploring the usage of both bioethanol and biodiesel. Currently, India is expanding Jatropha plantations to be used in biodiesel production. India is also setting a target of incorporating at least 5 % bioethanol into its transportation fuel. China that is a major bioethanol producer in Asia has a task plan for 15 % bioethanol incorporation into transport fuels. In the developing countries, biomass like cattle dung, wood, and other agricultural wastes are used extensively as fuel for cooking and heating. IEA claims that biomass energy provides for 30 % of energy supply in developing coun­tries for over 2 billion people. In spite of the many advantages of using biofuels for transportation and energy supply, there exits several technical issues that need to be resolved before biofuels can enter into the market with a cost equivalent to gasoline.

There are some common issues related to the use of liquid biofuels. Higher amount of alcohols in petrodiesel fuel blends is reported to cause corrosion of components in aluminum-based designs; this corrosion can be minimized with the addition of water to the blends; tests based on this concept showed that when water content was up to 1 %, there was no evidence of corrosion; only material discolouration was visualized. Biodiesel under low-temperature conditions showed molecular aggregation and formed crystals. Biodiesel usually contains small quan­tities of water, which arise during trans-esterification attributing to the occurrence of mono — and diglycerides because of incomplete reactions. These molecules act as an emulsifying agent making very small quantity of water miscible. Presence of water reduces fuel efficiency causing more smoke, leads to corrosion of fuel system components. Water presence can also interfere with the production process and may also impact the additives used.

On the other hand, butanol is toxic and its production and usage needs to undergo Tier 1 and Tier 2 health effects testing as per the EPA guidelines. As of 2010 food grade algae cost $5,000/tonne, this is attributed to high capital and operating costs, which may impact its contribution as a second-generation biofuel crop. The US Department of Energy estimates that 15,000 square miles of land will be required for algal cultivation if it has to augment replacement of conventional fuel in the USA. The USA alone consumes nearly 1 million barrels/day of conventional biofuels, and the world consumes about 2 million barrels/day. This number will certainly increase twofold to threefold in the next 20-30 years. However, most conventional biofuels (use first-generation feedstock) are highly government subsidized, which mean they are not economically sustainable, except ethanol from Brazil. Therefore, significant technical challenges must be overcome to ensure that biofuels can become economi­cal and affordable at large scale worldwide. The future of biofuels largely depends on the price of biomass and oil-based fuels, which in turn will increase as the demand for biofuels rises. Therefore, technological breakthroughs in the non-food feedstocks development are the most important challenge that needs to be resolved.

Synthesis and Acidity Enhancement of SBA-15

SBA-15 molecular sieve was prepared according to a procedure reported by Ooi and Bhatia (2007). In 300 mL of deionized water and 40 mL of hydrochloric acid (37 %) for 1 h at 323 K, 9.8 g of triblock copolymer poly(ethylene oxide)- poly(propylene oxide)-poly(ethylene oxide) (average molecular weight = 5,800) was dissolved with stirring. Next, 21.7 g of tetraethylorthosilicate was added and stirred for another 10 min. The mixture was then heated at 333 K and then at 373 K for 24 h under stirring. The solid product obtained was filtered, dried at 100 °C, and then calcined in air at 500 °C. Four grams of SBA-15 was dispersed in 100 mL solution of AlCl3 and refluxed at 353 K with stirring for 2 h. The aluminum-containing mesoporous catalyst was then filtered, thoroughly washed with deionized water, dried at room temperature, and finally calcined at 823 K for 4 h.

The Biofuel Industry Concentration in Brazil Between 2005 and 2012

Everton Anger Cavalheiro

Abstract Biofuel has come up as an important alternative to diversifying the global energy matrix, with economic, social, and environmental impact. Currently, Brazil is the main supplier and one of the top consumers of biofuels in the world, and has prioritized the use of soy as a raw material for the biofuel industry, as well as the sugarcane for producing ethanol; both industries use more than 8 million hectares of cropped land and employ over 1 million people every year. Considering the impor­tance of this subject for the energy matrix and Brazilian economy, we sought to ana­lyze the concentration level for each one of these industries, as well as its impact in pricing. The results point to a low concentration of the biodiesel market, where its production is centralized in four Brazilian states: Goias, Mato Grosso, Rio Grande do Sul, and Sao Paulo. This low concentration implies high competitiveness and homogenous average prices in the last couple of years (2011 and 2012), for com­panies holding 80 % of the market, as well as other firms in this industry. On the other hand, the industrial concentration level of the ethanol distribution channels has significantly grown, thus implying a significant and positive correlation between the increase of concentration and the increase of the contribution margin in this industry.

Keywords Biofuel • Biodiesel • Ethanol • Industry concentration

1 Introduction

Biodiesel has come up as an important alternative to diversifying the energy matrix in the world, where nations have tried to decrease their oil and oil derivatives dependence. Furthermore, the use of biodiesel has generated several economic, social, and environmental advantages, since it can generate both employment

E. A. Cavalheiro (H)

Federal University of Pelotas, Pelotas, Brazil e-mail: eacavalheiro@hotmail. com

A. Domingos Padula et al. (eds.), Liquid Biofuels: Emergence, Development and Prospects, Lecture Notes in Energy 27, DOI: 10.1007/978-1-4471-6482-1_4, © Springer-Verlag London 2014

and rent, it can decrease greenhouse gases emission, and it can also increase a country’s currency value in productive countries, both by exporting product and by reducing oil imports.

On the other hand, biodiesel has raised discussion since some evidence points to a causality relationship between biodiesel and agricultural commodities prices (Senauer 2008; Zhang et al. 2009, 2010). No matter what forces are oper­ating this system, it is crucial to understand the concentration level of this new Brazilian industry, while expecting it to become more and more important for both Brazilian and global energy matrix, as stated by MME (2010), which indi­cates that biodiesel will account for about 8 % of the transportation fuel global consumption in 2,035, a significant increase when compared to 3 % in 2009, for example.

Furthermore, despite being recent, the Brazilian biodiesel industry represents billions of dollars per year and is currently responsible for 5 % of the fuel used in Brazilian transportation, which currently demands 17 million biodiesel barrels/ year. If we consider that around 80 % of the raw material comes from soy, we have 12 % of the total soy crops today (around 27.2 million hectares, according to CONAB (2013) destined to supplying this important national industry.

Brazil is the number one user of biofuel when considering the total con­sumed by vehicles in the national freight, and it comes in as number two, con­sidering volume, after the USA. It is also the largest ethanol exporter in the world. This performance reflects the weather conditions and the technology developed by companies and institutions in the country. This segment accounted for, in 2012, the production on 27.78 million cubic meters of ethanol and bio­diesel in Brazil.

For 2012-2013 (from April 2012 to March 2013), the central-southern region alone exported 3.333 billion cubic meters of ethanol, and the main destinations are the USA (21 %), the Caribbean (31 %), and the European Union (31 %), where the sugar-alcohol exports alone generated US$14,601 billion in 2012-2013. These figures are the result of over a million people working in the area. Despite de expressive mark, the sugarcane for the production of ethanol—the main biofuel currently used in Brazil—takes up a relatively small area in Brazil: around 4.85 million hectares of cropped land.

Considering this problem, and considering the hypothesis that the concentra­tion level increases represents a decrease in the industry competitiveness, creat­ing opportunities for firms to price differently, we established the following research problem: what is the Brazilian biofuels industry concentration level like? Additionally, we tried to evaluate the concentration level of this industry for each one of the five Brazilian regions, the installed capacity usage level, as well as the possible effects of the industrial concentration in market prices.

In order to answer the research problem, we initially sought to show the con­cepts related to the market concentration, as well as their impacts for an industry. Subsequently, we discussed the biodiesel industry model and the possible infla­tionary pressures on food. Then, we presented this research’s method, and the results found.

Terminology

Before delving into the issues signalled above, it will be necessary to devote some attention to definitions. For example, the various types of biofuel will need to be explained, together with the crops normally employed in their respective production, for this has significant impacts on their sustainability credentials. Attention also needs to be paid to what sort of biomass is optimal for the produc­tions of both fuel types. The production processes, however, will be discussed later under ‘Lifecycle Analysis’ (i. e. Sect. 4).

Current Status of R&D in Biochemical Conversion of Second — and Third-generation Feedstocks to Biofuels

In the recent years, extensive research on biofuels production from second — and third-generation feedstocks has demonstrated remarkable achievements in terms of efficient enzyme system, microorganisms, innovative conversion technologies, and newer strategies of process integration. Table 5 shows the state of the development of biofuels from second — and third-generation feedstocks. As evident from Table 5, each of the individual processes is at a different stage of development and unless all these processes reach the commercial stage, it is not possible to anticipate a full-scale commercial plant for liquid biofuels production that can be established in all parts of the world. However, recent advances in biofuels research and subsi­dies from government can make it possible in the coming years.

It should be noted that to make biofuels enter into the market and compete with gasoline, it is important that cost is significantly reduced and liquid biofuels should be able to sustain without any government subsidies. Moreover, both private and public sectors should participate actively to realize the liquid biofuels industry to supply the demand of fuels for the future world and upcoming generations. The IEA projects that sugarcane ethanol and advanced biofuels could provide up to 9.3 % of total transportation fuels by 2030 and up to 27 % by 2050. But to achieve these pro­jections, at least a threefold to fivefold increase in land use for energy crops cultiva­tion and significant yield improvement in developing countries is needed.

Table 5 State of development of biochemical conversion route for second — and third-generation liquid biofuels production [adapted from IEA (2008)]

Individual process

Key objectives

State of development

Pretreatment

Properly size the material Produce ideal bulk density Remove dirt and ash Rapid depressurization to explode fiber Open the fiber structure

Demonstration/commercial but need optimization for different feedstocks and downstream processing

Fractionation

Cyclone to separate solids from vapors

R&D

Enzyme production

Cost and processing rate are key factors

Commercial but needs further cost reductions to reach USD 0.02-0.03Л of ethanol

Enzymatic hydrolysis

Produce C6 and C5 sugars Reduce viscosity

Early demonstration

Hexose fermentation

Standard yeast

Commercial

Pentose fermentation

Standard yeast is not suitable. New microorganisms dictate yield and rate. This affects feedstocks and capital expenditure on plant

Research/pilot plant moving toward commercialization

Ethanol recovery

Distillation to obtain 99.5 % ethanol

Commercial

Lignin recovery and

Separate lignin and other solids

Research/pilot plant co-

applications

Combust for heat and power or to produce biomaterial co-products

products to improve economic performance

Waste treatment

Detoxification/biorefinery of waste effluent

Research/commercial

Lipid extraction from algal biomass

Develop efficient method for lipid production and extraction from algal biomass

R&D

Cellulosic algal biomass

Cultivate algal biomass that can produce/accumulate cellulose components in cell mass

R&D

A Comparison Between Ethanol and Biodiesel Production: The Brazilian and European Experiences

Pery Francisco Assis Shikida, Adele Finco, Barbara Fran^oise Cardoso, Valdir Antonio Galante, Daliane Rahmeier, Deborah Bentivoglio and Michele Rasetti

Abstract Industrialized countries’ dependence on fossil fuels has been distressing for a long time for countries that do not have self-sufficiency, whether for environ­mental, economic, geopolitical, or other reasons. In this context, it is understood that the burning of fossil fuels contributes to greenhouse gas emissions (GHG) increasing the risk of intensifying climatic disturbances that can deteriorate the processes of production, consumption, and welfare in the world. Therefore, the development of alternative energy sources can provide solutions for the gaps, since reducing exposure to the vulnerability of supply and price volatility, environmental issues, and even the development of new investment opportunities in these coun­tries. This is due to the possibility of developing innovations in the production and processing industry, which would contribute to the economic activity. Thus, increasing the use of bioenergy is one of the existing ways to reconcile the need to [7] [8]

expand the supply of energy with the slowdown in global warming, i. e., the most important and disseminated use would be the biomass power generated by the consumption of biofuels, once it reduces GGE emissions.

1 Introduction

Global ethanol and biodiesel production are projected to expand at a slower pace than in the past. Ethanol markets are dominated by the USA, Brazil, and, to a smaller extent, the European Union. Biodiesel markets will likely remain domi­nated by the European Union and followed by the USA, Argentina, and Brazil.

The world biofuels production reached almost 124 billion liters in 2011; 80 % of that global production of liquid biofuels consists of ethanol and 20 % consists of biodiesel. The European Union produced in 2011 about 9.5 million metric tons of biodiesel, but in 2011, the production decreased about 10 % compared to 2010. However, the share of biodiesel is rapidly increasing due to emergence of new pro­ducing countries in Southeast Asia. The USA and Brazil are the largest ethanol producers, with 54 and 34 % of global ethanol output in 2009, respectively; while the European Union accounts for 57 % of global biodiesel production.

Brazil is the world’s second biggest producer of fuel ethanol (about 23 billion liters in 2011) and the world’s biggest exporter of fuel ethanol. The production started in the early 1970s by a program which led to the development caused by local automobile companies with flex-fuel engine technology. Presently, around half of all Brazilian cars use these hybrid engines, which can run with any mixture of pure ethanol and gasohol (around 80 % gasoline and 20 % ethanol). In 2010, cars used nearly equal volumes of gasoline and ethanol.

The chapter aims at revisiting the recent developments in biofuels markets and their economic and environmental impacts. The analysis compares the perfor­mance of ethanol versus biodiesel produced in Brazil and Europe, respectively.

This chapter is organized as it follows: Sects. 2 and 3 discuss the scenario of Brazilian ethanol and European biodiesel in terms of policies, production, sup­ply, and demand. Section 4 examines the environmental impacts of both biofuels. Finally, we draw key conclusion.

Raw Material Prices

The prices for feedstocks are critical for the economically viable production of bio­fuels. In addition to raw material prices, crude oil as key competitor product also influences the profitability of biofuels. Prices for both are interrelated. Increasing oil prices tend to fuel demand for alternative sources of energy and thus the prices for raw materials. A positive correlation between the prices for crude oil and global grain commodities has been demonstrated in a model by Chen et al. (2010).

In order to project raw material prices for biofuels, we analyse the relation between the price of biofuel raw materials (pB) of type k (maize, wheat, rapes oil, palm oil and wood) and past crude oil prices (pO) while also considering other major drivers of raw material prices, including a price index for agricultural prod­ucts (pA), growth in world population (POP), growth in wealth (per capita income: GDP/POP), change in energy consumption per capita (EN/POP) and global infla­tion (pGDP). The linear regression model to be estimated reads as follows:

pBk, t = a + ei, kpOt + P2,kPAt + e3,kpGDPt + xi, k POPt + X2,k GDP/POPt

+ X3,kEN/P°Pt + &k, t > (1)

with t being a time index for months, a being a constant, в and x being parameters to be estimated and є being a time and k-specific error term. We take the following monthly price data for five different biofuel raw materials k.

• Maize: US No. 2 Yellow, FOB Gulf of Mexico ($/t)

• Wheat: No. 1 Hard Red Winter, ordinary protein, FOB Gulf of Mexico ($/t)

• Rapes oil: Crude, fob Rotterdam ($/t)

• Palm oil: Malaysia Palm Oil Futures (first contract forward) 4-5 % FFA ($/t)

• Wood: average price ($/m3) for softwood (average export price of Douglas Fir, U. S. Price) and hardwood (Dark Red Meranti, select and better quality, C&F UK port)

The data for crude oil prices were obtained as an average of Dated Brent, West Texas Intermediate and Dubai Fateh (Euro/barrel). Raw material prices were taken

Year

Crude oil

Maize

Wheat

Rapeseed oil

Palm oil

Wood

(Euro/barrel)

(Euro/t)

(Euro/t)

(Euro/t)

(Euro/t)

(Euro/t)

(Euro/m3)

(Euro/t)

1982

29

362

98

146

380

333

172

286

1983

31

217

141

163

525

435

179

298

1984

34

239

159

179

807

704

228

380

1985

34

243

141

170

683

524

198

331

1986

14

98

86

111

350

206

176

294

1987

15

107

62

93

286

233

219

364

1988

12

84

86

117

431

290

214

356

1989

15

109

95

144

406

247

278

464

1990

17

120

81

101

319

178

269

449

1991

15

106

83

99

320

215

285

474

1992

14

99

76

111

296

238

308

513

1993

14

99

85

117

385

260

433

722

1994

13

94

90

125

517

362

467

779

1995

13

93

94

135

482

410

396

661

1996

16

112

127

161

436

362

407

678

1997

17

120

103

140

495

431

419

699

1998

12

84

92

114

568

541

344

573

1999

17

121

84

105

399

350

422

703

2000

31

218

95

123

373

280

476

793

2001

27

193

100

141

437

266

430

717

2002

27

189

106

157

509

379

421

701

2003

26

183

94

130

537

365

372

619

2004

30

217

90

127

576

351

366

610

2005

43

306

79

122

578

295

392

654

2006

51

365

97

153

678

332

433

721

2007

52

369

120

186

737

524

412

686

2008

65

463

151

220

961

578

406

676

2009

44

314

119

161

614

462

394

657

2010

59

423

140

168

760

646

426

709

All prices are average prices per year Ein barrel Rohol sind 159 L

Die Dichte von Rohol schwankt zwischen 0.8 bis 1 kg/l—beim Vergleich mit Rohol rechnet man

im Allgemeinen mit einer Dichte von 0.883 kg/l

Als mittlere Dichet von Holz wurde 600 kg/m3 angenommen from www. indexmundi. com. Table 1 shows average annual prices for the five biofuel feedstocks as well as for crude oil, based on monthly data from April 1982 to April 2010. The historical price overview shows significant differences in price developments for the different types of raw material. For example, the palm oil price has doubled between 2006 and 2010, while during the same time prices for wood remained almost stable.

Annual data on population, GDP, energy consumption, inflation and agri­cultural prices were taken from the ‘World Development’ and converted into monthly data through linear interpolation. We measured all prices, GDP and

energy consumption in US Dollars and converted them into Euros using monthly exchange rate averages.

An ARMAX (Harvey 1993) modelling approach with a one month autoregres­sive term of the structural model disturbance and additive annual effects was used (see the results in Table 2). It is obvious that the price of crude oil is significantly correlated to prices for biofuel feedstock. Crude oil has the weakest impact on prices for wheat and maize, while rapes oil and palm oil prices are heavily influ­enced. The influence on wood is in between these two groups. The results indi­cate that both rapes and palm oil have been used as energy inputs to a significant degree in the past and are therefore more closely related to oil price changes than wheat and maize. These are still predominantly used as input for food production.

Future prices for biofuel feedstock in 2015 and 2020 are based on the estimation results in Table 2. For the calculation, projected values for all independent vari­ables are necessary. In regard to prices for crude oil, we refer to oil price scenarios that have been published by IEA (2007) and the International Energy Outlook. We then investigate the effects of crude oil prices per barrel of Euro 50, Euro 100, Euro 150 and Euro 200 in 2020. For 2015, crude oil prices are calculated through linear interpolation of the 2011 value and the 2020 scenario. In regard to the other vari­ables, we assume a 1 % p. a. increase in world population, a 2.5 % p. a. increase in GDP per capita, a 1.25 % p. a. increase in energy consumption per capita, a 5 % p. a. increase in agricultural prices and a global inflation of 6 % p. a. These assump­tions are close to the average rate of change of each variable during 1982 and 2010. For simplicity reasons, business cycle effects are not taken into consideration.

Dependent on different crude oil price developments, biofuel raw material prices for 2015 and 2020 are determined. Table 3 reports projected prices for 2015 and 2020 as well as actual and predicted prices in 2010. Prices are expressed in Euros per tonne, as production cost scenarios use tonne units for all material inputs. For crude oil, we assume a mass density factor of 0.883 kg/L and for wood a mass density factor of 0.6 kg/dm3. Except for palm oil, predicted 2010 prices are higher than they really were. This indicates that the price level in 2010 was lower than one would have expected if prices had followed the typical development of the past three decades. A calming effect on commodity due to the economic crisis may be one of the main reasons for that. The 2010 price level for all raw materials, except palm oil, was below the peak of the pre-crisis level in 2006 and 2008, while crude oil prices in 2010 were close to the pre-crisis peak. As mentioned before, we refrain from considering any type of business cycle effects on prices but focus on longer term trends in raw material prices. For this reason, we do not adjust projected prices for 2015 and 2020 to the ‘prediction error’ in 2010 but consider the higher predicted prices for 2010 (and consequently for 2015 and 2020) as reflecting an upcoming upwards trend of commodity prices in case the world economy recovers.

Wheat, rapes oil and maize prices are expected to undergo the largest rise until 2020. In the Euro 50 scenario, prices for these three types of biomass will increase by 89, 85 and 66 %, respectively, compared with the actual prices in 2010, which were rather low. In the Euro 200 scenario, price advances will be significantly higher. Changes are all above 100 %. In regard to palm oil, prices are expected to

Table 2 Results of ARMAX model estimations

 

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Подпись: G. Festel et al.

Table 3 Actual raw material prices for 2010 and estimated raw material prices for 2015 and 2020 (annual averages)

Year

Crude oil

Maize

Wheat

Rapeseed Palm oil oil

Wood

(Euro/

barrel)

(Euro/t) (Euro/t) (Euro/t) (Euro/t)

(Euro/t)

(Euro/m3)

(Euro/t)

2010

(actual) 59

423

140

168

760

646

426

709

(predicted) 59

423

159

211

910

591

468

780

2015

50

356

184

245

1,079

548

381

635

100

712

213

284

1,273

731

441

734

150

1,068

242

323

1,467

913

500

834

200

1,425

271

362

1,661

1,095

560

933

2020

50

356

232

317

1,405

582

286

476

100

712

261

356

1,599

764

345

576

150

1,068

290

395

1,793

947

405

675

200 1,425 319 Rate of change (%) over actual level in 2010

434

1,987

1,129

465

775

2020

50

-16

66

89

85

-10

-33

-33

100

68

87

112

110

18

-19

-19

150

153

108

135

136

46

-5

-5

200

237

129

159

161

75

9

9

All prices are average prices per year

remain stable in the Euro 50 scenario but increase substantially in the Euro 200 scenario. This reflects the stronger link between crude oil and palm oil prices. As for wood, all scenarios except the Euro 200 scenario expect tumbling prices. The latter estimates constant prices for the time period between 2010 and 2020.

Waste material is another important group of raw material for biofuels. However, there are no world market prices available, due to waste rarely being traded internationally, because of high transport costs per unit and small unit val­ues. In our scenario analysis, we assume that the prices for waste lignocellulosic material are constantly 1/4 of the price of maize and the price for waste oil is 1/2 of the price of palm oil. At this point, we assume that producers are price takers and that production functions are linear homogenous.

Climate Threats and Technological Opportunities

It is important not to lose sight of the impact that climate change itself will have on biofuels into the future, together with determining the most appropriate place for biofuels in the long-term battle to reduce global GHG emissions. This section deals with these two issues.

4.2 Effects of Climate Change

It is uncertain whether existing current climatic conditions will prevail, with many scientists contending that anthropogenic climate change is already taking effect across the globe (Cook et al. 2013). There are a number of critical factors associ­ated with climate change that need to be taken into account. First, and as intro­duced above, there may be increased uncertainty with regard to rainfall patterns. This will problematize when to plant with annual crops (such as those used for first-generation biofuels), and will also place increased pressure on water use, with potential social repercussions outside the agricultural arena. Second, there may be increased and more severe meteorological phenomena, with floods wip­ing out entire fields, and storms damaging or destroying entire harvests (Charles et al. 2009). Uncontrolled fires resulting from drought, thunderstorm activity or human action could also have similar effects. Third, there may be an increased severity and incidence of pestilence, with changed climatic conditions making crops destined for biofuel production more susceptible to pest outbreaks (Malcolm et al. 2012). This would have the added environmental implication that there could potentially be an increased need to employ pesticides, herbicides or fungicides, with all the negative outcomes associated with the use of these materials signalled above compounded by increased chemical usage.

Taken together, these issues suggest that it will be more difficult to plan for weather — and climate-related phenomena into the future. Nations will clearly be unable to rely solely on domestic biomass cultivation for their biofuel needs (Larson 2008). It follows that increased energy security associated with biofuel production will need to be tempered with the understanding that existing agri­cultural techniques certainly do not guarantee constant and predictable harvests in the face of regular climatic uncertainty. Yet climate change, as is generally expected, will exacerbate this high level of uncertainty, regardless of whether it is anthropogenic or otherwise, or indeed a combination of both man-made and natu­ral processes. Regardless of these issues, it is essential that biofuel policy takes a path that does as much as possible to ensure that it assists with anthropogenic cli­mate change mitigation, rather than exacerbating the problem.