Conversion of Oil Palm Empty Fruit Bunch to Biofuels

Anli Geng

Additional information is available at the end of the chapter http://dx. doi. org/10.5772/53043

1. Introduction

Crude palm oil production is reaching 48.99 million metric tonnes per year globally in 2011 and Southeast Asia is the main contributor, with Indonesia accounting for 48.79%, Malaysia 36.75%, and Thailand 2.96% (Palm Oil Refiners Association of Malaysia, 2011). Oil palm is a multi-purpose plantation and it is also an intensive producer of biomass. Accompanying the production of one kg of palm oil, approximately 4 kg of dry biomass are produced. One third of the oil palm biomass is oil palm empty fruit bunch (OPEFB) and the other two thirds are oil palm trunks and fronds [13].

image198

Figure 1. Oil palm and oil palm empty fruit bunch.

The supply of oil palm biomass and its processing by-products are found to be seven times that of natural timber [4]. Besides producing oils and fats, there are continuous interests in using oil palm biomass as the source of renewable energy. Among the oil palm biomass, OPEFB is the most often investigated biomass for biofuel production. Traditionally, OPEFB is used for pow­er and steam utilization in the palm oil mills, and is used for composting and soil mulch. Di­rect burning of OPEFB causes environmental problems due the incomplete combustion and

the release of very fine particles of ash. The conversion of OPEFB to biofuels, such as syngas, ethanol, butanol, bio-oil, hydrogen and biogas etc., might be a good alternative and have less environmental footprint. The properties of OPEFB is listed in Table 1 [5].

Literature values

% (w/w)

Measured

% (w/w)

Method

Components

Cellulose

59.7

na

na

Hemicellulose

22.1

na

na

Lignin

18.1

na

na

Eelemental analysis

Carbon

48.9

49.07

Combustion analysis

Hydrogen

6.3

6.48

Nitrogen

0.7

0.7

Sulphur

0.2

<0.10

Oxygen

36.7

38.29

By difference

K

2.24

2.00

Spectrometry

K2O

3.08-3.65

na

na

Proximate analysis

Moisture

na

7.95

ASTM E871

Volatiles

75.7

83.86

ASTM E872

Ash

4.3

5.36

NREL LAP005

Fixed carbon

17

10.78

By difference

HHV (MJ/kg)

19.0

19.35

Bomb calorimeter

LHV (MJ/kg)

17.2

na

na

Notes: na — not available.

Table 1. Properties of oil palm empty fruit bunch

While all the OPEFB components can be converted to biofuels, such as bio-oil and syngas through thermo-chemical conversion, cellulose and hemicellulose can be hydrolysed to sug­ars and subsequently be fermented to biofuels such as ethanol, butanol, and biogas etc. Al­though many scientists around the world are developing technologies to generate biofuels from OPEFB, to-date, none of such technologies has been commercialized. This is largely due to the recalcitrance of the OPEFB and therefore the complexity of the conversion tech­nologies making biofuels from OPEFB less competitive than the fossil-based fuels. Continual efforts in R&D are still necessary in order to bring such technology to commercialization. The aim of this paper is to review the progress and challenges of the OPEFB conversion technologies so as to help expedite the OPEFB conversion technology development.