Как выбрать гостиницу для кошек
14 декабря, 2021
Anli Geng
Additional information is available at the end of the chapter http://dx. doi. org/10.5772/53043
Crude palm oil production is reaching 48.99 million metric tonnes per year globally in 2011 and Southeast Asia is the main contributor, with Indonesia accounting for 48.79%, Malaysia 36.75%, and Thailand 2.96% (Palm Oil Refiners Association of Malaysia, 2011). Oil palm is a multi-purpose plantation and it is also an intensive producer of biomass. Accompanying the production of one kg of palm oil, approximately 4 kg of dry biomass are produced. One third of the oil palm biomass is oil palm empty fruit bunch (OPEFB) and the other two thirds are oil palm trunks and fronds [1—3].
Figure 1. Oil palm and oil palm empty fruit bunch. |
The supply of oil palm biomass and its processing by-products are found to be seven times that of natural timber [4]. Besides producing oils and fats, there are continuous interests in using oil palm biomass as the source of renewable energy. Among the oil palm biomass, OPEFB is the most often investigated biomass for biofuel production. Traditionally, OPEFB is used for power and steam utilization in the palm oil mills, and is used for composting and soil mulch. Direct burning of OPEFB causes environmental problems due the incomplete combustion and
the release of very fine particles of ash. The conversion of OPEFB to biofuels, such as syngas, ethanol, butanol, bio-oil, hydrogen and biogas etc., might be a good alternative and have less environmental footprint. The properties of OPEFB is listed in Table 1 [5].
Literature values % (w/w) |
Measured % (w/w) |
Method |
|
Components |
|||
Cellulose |
59.7 |
na |
na |
Hemicellulose |
22.1 |
na |
na |
Lignin |
18.1 |
na |
na |
Eelemental analysis |
|||
Carbon |
48.9 |
49.07 |
Combustion analysis |
Hydrogen |
6.3 |
6.48 |
|
Nitrogen |
0.7 |
0.7 |
|
Sulphur |
0.2 |
<0.10 |
|
Oxygen |
36.7 |
38.29 |
By difference |
K |
2.24 |
2.00 |
Spectrometry |
K2O |
3.08-3.65 |
na |
na |
Proximate analysis |
|||
Moisture |
na |
7.95 |
ASTM E871 |
Volatiles |
75.7 |
83.86 |
ASTM E872 |
Ash |
4.3 |
5.36 |
NREL LAP005 |
Fixed carbon |
17 |
10.78 |
By difference |
HHV (MJ/kg) |
19.0 |
19.35 |
Bomb calorimeter |
LHV (MJ/kg) |
17.2 |
na |
na |
Notes: na — not available. |
Table 1. Properties of oil palm empty fruit bunch |
While all the OPEFB components can be converted to biofuels, such as bio-oil and syngas through thermo-chemical conversion, cellulose and hemicellulose can be hydrolysed to sugars and subsequently be fermented to biofuels such as ethanol, butanol, and biogas etc. Although many scientists around the world are developing technologies to generate biofuels from OPEFB, to-date, none of such technologies has been commercialized. This is largely due to the recalcitrance of the OPEFB and therefore the complexity of the conversion technologies making biofuels from OPEFB less competitive than the fossil-based fuels. Continual efforts in R&D are still necessary in order to bring such technology to commercialization. The aim of this paper is to review the progress and challenges of the OPEFB conversion technologies so as to help expedite the OPEFB conversion technology development.