Как выбрать гостиницу для кошек
14 декабря, 2021
The biomass can also be fermented to yield liquid alcohol fuels. If one assumes that 50% biomass is cellulose and all cellulose is converted into fermentable glucose, then with reaction C6H12O6 + 3H2O [L] = 3C2H5OH [L] + 3O2 or 1 kg cellulose + 0.3 kg of H2O = 0.77kg
Table 3.1. Biogas yields from different biomass. |
|
Feedstock (manure) |
CH4 [Yield, liters/ liter of VS added] |
Dairy |
0.034-0.118 |
Beef |
0.055-0.082 |
Swine |
0.058-0.111 |
Wheat stems |
0.071 |
Wheat roots |
0.047 |
Tomato |
0.060 |
Table 3.2. Estimation of growth of biomass with 6% |
conversion efficiency. |
Solar radiation and biomass growth |
|
1 gallon in m3 |
0.003785 |
Feed density [kg/m3] |
800 |
Ethanol density [kg/liter (lb/gallon)] |
0.788 (6.6) |
HHV ethanol [MJ/kg (BTU/lb)] |
167 (76000) |
Solar irradiance [W/m2] |
1200 |
Conversion efficiency [%] |
6 |
HHV biomass [kJ/kmole] |
2801000 |
Molecular weight biomass |
180 |
Cellulose% in biomass |
50 |
Conversion to ethanol [kg/g glucose] |
0.77 |
Cellulose to fermentable glucose |
1 |
Biomass production [tonnes/hectare/year] |
1459 |
Glucose [tonnes/hectare per year] |
730 |
Ethanol production [tonnes/hectare] |
562 |
Ethanol production [gallons/hectare] |
185525 |
Ethanol [kg per tonne biomass] |
385 |
Ethanol [gallon per tonne biomass] |
127 |
ethanol + 0.53 kg O2, ethanol production per tonne biomass is 125 gallons per tonne of biomass which is close to the reported theoretical value of 124 gallons/dry tonne of corn grain (Ragauskas). With 1 hectare = 10,000 m2, and solar irradiation of 1200 W/m2 and photosynthesis efficiency of 6%, the biomass production is 1460 tonnes per year per hectare assuming a heat value of
2,800,0 kJ/kmole, and with a molecular weight M = 180 kg/kmole. Comparing it with switch grass whose production is 37 tonnes per hectare per year, the maximum ethanol yield is 48.1 m3 (183,000 gallons) per hectare per year with a heating value (HV) of 7.37 kJ/m3 (28,000 kJ/gallon). With a higher heating value (HHV) of gasoline about 32.9kJ/m3 (125,000kJ/gallon), 1 liter of ethanol is equivalent to 0.22 liter of gasoline. Estimation of biomass growth with 6% conversion efficiency and the yield of ethanol from biomass are tabulated in Table 3.2.