CATALYTIC UPGRADING TECHNOLOGIES FOR PYROLYSIS

VAPOURS AND LIQUIDS

6.1 INTRODUCTION

In all thermochemical conversion processes, catalysts are being increasingly used to enhance favourable reactions and inhibit unfavourable reactions. In addition, catalytic processes are both available and are being developed to upgrade the primary products of thermal conversion to higher quality and higher value fuels and chemicals as summarised in Table 6.1 for a range of thermally processed products. This study focuses on fast pyrolysis processes and liquid products as a means to increase the value of resultant products at minimal cost. While reference is made to many of the research activities involving the use of catalysts in biomass conversion (see, for example, 1), attention is focused on particular problems requiring short term solution to enable the benefits of these technologies to be realised.

Table 6.1 Catalytic Processes for Secondary Products

Secondary Droduct

Source

Catalytic Drocess

Status

Oxygenated Fuels

Methanol

Gasification

Synthesis

Commercial from syngas

Fuel alcohol

Gasification

Synthesis

Development

Hydrocarbon Fuels

Gasoline

Pyrolysis

Hydrotreating

Research

Pyrolysis

Zeolites

Research

Liquefaction

Hydrotreating

Research

Gasification

MTG#

Commercial from

Diesel

Pyrolysis

Hydrotreating

reformed natural gas Research

Pyrolysis

Zeolite + MOGD #

Research

Liquefaction

Hydrotreating

Research

Gasification

MOGD#

Research

Fuel oil

Pyrolysis

Stabilisation

Conceptual

Liquefaction

Stabilisation

Conceptual

Chemicals

Ammonia

Gasification

Synthesis

Commercial

Specialities

Pyrolysis

Extraction / Conversion

Development

Liquefaction

Extraction / Conversion

Research

Notes # MTG : Methanol To Gasoline process (Mobil)

MOGD : Methanol To Olefins, Gasoline and Diesel (Mobil)