Как выбрать гостиницу для кошек
14 декабря, 2021
Glycerolysis is a process in which the content of FFAs is reduced in feedstocks by combining FFAs with glycerin to create mono-, di-, and tri-glycerides as shown in the process flow diagram of Albemarl Corp (Figs. 18.4 and 18.5) [20]. The glycerin
—OH |
—OH |
—OH |
Glycerolysis |
||
—OH—————— ► |
—OH + |
—OCOR + |
R-COOH |
||
—OH |
—OCOR |
—OCOR |
—OCOR —OCOR + H2° —OCOR |
Glycerol |
Fig. 18.4 The glycerolysis reaction between glycerol and free fatty acids to produce glycerides |
is routed back to a reactor where it is combined with the high FFAs feedstock. The effluent of the glycerolysis process is a low FFAs feedstock, typically less than 1 %, suitable for alkaline transesteriflcation process under normal operating conditions. JatroDiesel, USA, offers a unit for the glycerolysis of acid feedstocks with different levels of FFAs. Glycerolysis with up to 100 % FFAs has been demonstrated at industrial scales while acid esterification process has been used for feedstocks with FFAs below 25 %, and stripping of FFAs has been used with 15 % FFAs or lower, prior to alkaline transesterification process for the production of biodiesel [20].