Glycerolysis of FFAs

Glycerolysis is a process in which the content of FFAs is reduced in feedstocks by combining FFAs with glycerin to create mono-, di-, and tri-glycerides as shown in the process flow diagram of Albemarl Corp (Figs. 18.4 and 18.5) [20]. The glycerin

OH

—OH

—OH

Glycerolysis

—OH—————— ►

—OH +

—OCOR +

R-COOH

—OH

—OCOR

—OCOR

—OCOR

—OCOR + H2°

—OCOR

Glycerol

Fig. 18.4 The glycerolysis reaction between glycerol and free fatty acids to produce glycerides

is routed back to a reactor where it is combined with the high FFAs feedstock. The effluent of the glycerolysis process is a low FFAs feedstock, typically less than 1 %, suitable for alkaline transesteriflcation process under normal operating conditions. JatroDiesel, USA, offers a unit for the glycerolysis of acid feedstocks with different levels of FFAs. Glycerolysis with up to 100 % FFAs has been demonstrated at indus­trial scales while acid esterification process has been used for feedstocks with FFAs below 25 %, and stripping of FFAs has been used with 15 % FFAs or lower, prior to alkaline transesterification process for the production of biodiesel [20].