Biodiesel from Algae

6.1 Introduction

Continued use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies and the contribution of these fuels to the accumulation of carbon dioxide in the environment. Renewable, carbon-neutral transport fuels are necessary for environmental and economic sustainability (Chisti 2007). Biodiesel can be carbon neutral and produced intensively on relatively small areas of marginal land. The quality of the fuel product is comparable to petroleum diesel and can be incorporated with minimal change into the existing fuel infrastructure. Innovative techniques, including the use of industrial and domestic waste as fertilizer, could be applied to further increase biodiesel productivity (Campbell 2008).

Algae, like corn, soybeans, sugar cane, wood, and other plants, use photosynthe­sis to convert solar energy into chemical energy. They store this energy in the form of oils, carbohydrates, and proteins. The plant oil can be converted into biodiesel; hence biodiesel is a form of solar energy. The more efficient a particular plant is at converting that solar energy into chemical energy, the better it is from a biodiesel perspective, and algae are among the most photosynthetically efficient plants on earth.

Algae can be a replacement for oil-based fuels, one that is more effective and has no disadvantages. Algae are among the fastest growing plants in the world, and about 50% of their weight is oil. This lipid oil can be used to make biodiesel for cars, trucks, and airplanes. Microalgae have much faster growth rates than terres­trial crops. The per-unit area yield of oil from algae is estimated to be between 20,000 and 80,000L/acre/year; this is 7 to 31 times greater than the next best crop, palm oil. The lipid and fatty acid contents of microalgae vary in accordance with culture conditions. Most current research on oil extraction is focused on microal­gae to produce biodiesel from algal-oil. Algal-oil can be processed into biodiesel as easily as oil derived from land-based crops.

The production of microalgal biodiesel requires large quantities of algal biomass. Macro — and microalgae are currently mainly used for food, in animal feed, in feed

A. Demirbas, M. Fatih Demirbas, Algae Energy DOI 10.1007/978-1-84996-050-2, © Springer 2010

for aquaculture, and as biofertilizer. A 1-ha algae farm on wasteland can produce over 10 to 100 times as much oil compared to any other known source of oil crops. While a crop cycle may take from 3 months to 3 years for production, algae can start producing oil within 3 to 5 d, and thereafter oil can be harvested on a daily basis (just like milk). Algae can be grown using sea water and nonpotable water on wastelands where nothing else grows. Algae farming for biofuels is expected to provide a conclusive solution to the food vs. fuel debate.

The production of biodiesel has recently received much attention worldwide. In order to resolve the worldwide energy crisis, seeking for lipid-rich biological materi­als to produce biodiesel effectively has attracted much renewed interest. Algae have emerged as one of the most promising sources for biodiesel production. It can be inferred that algae grown in CO2-enriched air can be converted into oily substances. Such an approach can contribute to solving the major problems of air pollution re­sulting from CO2 emissions and future crises due to a shortage of energy sources (Sharif Hossain et al. 2008).