Biohydrogen

The combustion products of hydrogen when it is burned completely with air consist of water, oxygen, and nitrogen. However, it has been suggested that hydrogen is too valuable to burn. Laboratory tests conducted on internal combustion engines burning hydrogen demonstrate good performance (Berry et al. 1996). In comparison with an engine burning gasoline, the emission of nitrogen oxides is far less for the engine — fueled hydrogen. The product of hydrogen combustion with air is water vapor and negligible pollution when the peak temperature is limited. Some oxides of nitrogen (NOx/ are formed at very high combustion temperatures (<2,300K); fortunately, the autoignition temperature of hydrogen is only 858 K.

Hydrogen has good properties as a fuel for internal combustion engines in au­tomobiles. Some of the characteristic properties of a hydrogen-air mixture that can definitely influence engine design and performance are low ignition energy, low density, wide range of ignition limits, high diffusion speed, and high flame speed (Plass Jr. et al. 1990).

The main disadvantage of using hydrogen as a fuel for automobiles is the huge on-board storage tanks that are required because of hydrogen’s extremely low den­sity. Hydrogen may be stored on board a vehicle as compressed gas in ultra-high- pressure vessels, as a liquid in cryogenic containers, or as a gas bound with certain metals in metal hydrides.

Hydrogen is one of the most promising alternative energy technologies. Hydro­gen can be generated in a number of ways, such as electrochemical processes, ther­mochemical processes, photochemical processes, photocatalytic processes, or pho­toelectrochemical processes (Momirlan and Veziroglu 1999, 2002). Biohydrogen production by anaerobic fermentation of renewable organic waste sources has been found to be a promising method for the recovery of bioenergy (Han and Shin 2004).

In this method, anaerobic bacteria use organic substances as the sole source of elec­trons and energy, converting them into hydrogen.

The use of hydrogen as a fuel for transportation and stationary applications is receiving much favorable attention as a technical and policy issue (Cherry 2004). Hydrogen gas is being explored for use in combustion engines and fuel-cell electric vehicles. It is a gas at normal temperatures and pressures, which presents greater transportation and storage hurdles than exist for liquid fuels. Several hydrogen tech­nologies are under development; the most promising of these is the fuel cell. Fuel cells use hydrogen, oxygen, a catalyst, and an electrolytic solution to produce energy in the form of heat and electricity.