Measurement of the performance of a PEFC unit

Based on the duration time, we measured the performance of a PEM-cell which is based on a PEFC unit for a smart phone. That is, using the result of output capability of a PEM-cell and the maximum duration time, we designed the cell area of a PEFC, and estimated the energy consumption for each function.

Here, in order to have a good reliability, 10 times experiments have been done for the following tasks: a talking, a SMS, music (MP3), a game, a web-site (internet) and an e-mail checking, respectively. In our experiments, we used the electric measurement device (AC/DC POWER HiTESTER 3334, HIOKI E. E. Corp.) to measure the voltage and the current, and the power which is obtained by these factors.

Next, for the purpose of estimating the cell performance, we measured the potential of a PEM-cell in varying currents. The apparatus consists of a PEM-cell (Micro Inc.) and a
potentiostat (HAB-151, Hokuto Denko Corp.). The size of the cell with low platinum loading electrodes (1.0 Pt mg/cm2) and Nafion® 115 is 4 cm2*3 cells. Using a potentiostat, 1) an open circuit voltage V0 [Volt] was measured and 2) the relationship of current density J vs. cell potential V was evaluated between approximately 200 mV / cell and an open circuit potential V0 . Also, H2 flow in anode was up to 20 ml/min and the concentration of H2 was 100 vol.% at a constant percentage (see Fig.8). Note that each parameter on the performance of a PEM-cell is decided at the condition which is not rate-limiting. In this case, we adopted the flow rate condition of 20 ml/min. The cathode was stayed at the atmospheric condition. The conditions in both the anode and cathode sides were not saturated by steam (Dowaki et al., 2010a, Dowaki et al., 2011b).

Next, the relationship between a cell’s potential and current density, in the low and intermediate current density region of a PEM-cell, has been shown to obey the following Eq. (19) (Kim et al., 1995). Note that the result was shown by the condition of a single PEM — cell.

Подпись: Fig. 8. Relationship between current density and a cell voltage in the single PEM-cell.

Current density [mA/cm2]

Next, due to the questionnaire for smart phone users (see Fig. 7), the energy consumption for each function and the performance of PEFC using a PEM-cell experimental result, we estimated CO2 emission on basis of LCA methodology. Using Eq. (19), the H2 flow rate in practice use is able to be calculated. Here, a PEFC would be operated between 1.17 and 2.63 Volt. The specific energy consumption in each function was between 0.39 and 37.7 Nml/min.