SELF-ARRANGEMENT OF STRUCTURAL AND DEFECTIVE STATES IN NON-EQUILIBRIUM SYSTEMS

At high hydrogen concentrations in the residual medium, the (EIHIS, EIHCIS, MADHM) effects play a positive role of a peculiar safety device against the excessive heat flow during hot time of the day.

These effects perfectly match the present-day concepts in the field of quantum chemistry [42] and classical thermodynamics [43-47]. In accordance with the classification of classical thermodynamics, a chemically active open complicated thermodynamic system has been considered in this review [45]. The set of dissipative processes being considered vividly demonstrates the non-equilibrium ability to serve as a source of ordering through fluctuations. The (EIHIS, EIHCIS, MADHM) effects are the manifestation of self-arrangement in non-equilibrium systems. The discovery of these effects [6,7] shows the non-suitability of the description formalism of similar thermodynamic systems with superinsulation in the field of instability based on the Boltzman principle. During the experiments on reduction of the hydrogen concentration in the vacuum cavity of the filled cryogenic reservoir, the consecutive oscillatory and bifurcation processes of the residual hydrogen pressure variation have been noted.

So some instabilities, secondary bifurcations of time-periodic cycles observed have been noted. These bifurcations in case of a three-molecular models can be obtained analytically.

The investigation conducted has shown that a gradual decreasing of the amplitude of superinsulation heat conduction oscillations occurs at reduction of the residual hydrogen concentration.