Water content and sediment

The Brazilian and American standards combine water content and sediment in a single parameter, whereas the European standard treats water as a separate parameter with the sediment being treated by the Total Contamination property. Water is introduced into biodiesel during the final washing step of the production process and has to be reduced by drying. However, even very low water contents achieved directly after production do not guarantee that biodiesel fuels will still meet the specifications during combustion. As biodiesel is hygroscopic, it can absorb water in a concentration of up to 1000 ppm during storage. Once the solubility limit is exceeded (at about 1500 ppm of water in fuels containing 0.2% of methanol), water separates inside the storage tank and collects at the bottom (Mittelbach 1996). Free water promotes biological growth, so that sludge and slime formation thus induced may cause blockage of fuel filters and fuel lines. Moreover, high water contents are also associated with hydrolysis reactions, partly converting biodiesel to free fatty acids, also linked to fuel filter blocking. Finally, corrosion of chromium and zinc parts within the engine and injection systems have been reported (Kosmehl and Heinrich, 1997). Lower water concentrations, which pose no difficulties in pure biodiesel fuels, may become problematic in blends with fossil diesel, as here phase separation is likely to occur. For these reasons, maximum water content is contained in the standard specifications.