Plant oils

There has been interest in the use of virgin plant oils to fuel diesel engines. At least 2,000 oleaginous species, growing in almost all climates and latitudes, have been identified. There are more than 350 plant species that produce oil that could be used to power diesel engines (Goering et al., 1982). The plant oils are made up of 98% triglycerides and small amounts of mono — and diglycerides. There are basically two types of vegetable oils: those in which the majority of fatty acids are in C12 (e. g., palms) and those in which the majority of fatty acids are in C18.

The direct use of plant oils (and/or blends of these oils with fossil fuels) has generally been considered to be unsatisfactory or impracticable for both direct and indirect diesel engines. Obvious problems include their high viscosity (Ramadhas et al., 2005), acidic composition, free fatty acid content, tendency to deposit carbon, tendency for lubricating-oil thickening, and gum formation because of oxidation polymerization during storage and combustion. When blending vegetable oils with fossil diesel fuel, the viscosity can be extensively adjusted. Based on EN 14214 recommendations, the maximum blending rate of most vegetable oils is B30 (30% plant oil/fossil diesel, v/ v) (Abolle et al., 2008). The oil viscosity (because of the presence large triglycerides) can also be reduced by pyrolysis, which produces an alternative fuel for diesel engines (Lima et al., 2004). Using plant oils in blends also significantly increases their cloud points and thus limits their use to climatically compatible countries.