RESINS WITH HIGHER ALGAL BINDING CAPACITY FOR DIRECT TRANSESTERIFICATION

While these studies were initiated and largely carried through using Am — berlite, it became apparent through efforts to develop better resins that the binding capacity of Amberlite for algae is generally quite low [25]. It is particularly low for KAS603, which gave the highest yields of FAME rela­tive to its dried weight. A comparison of Amberlite to other functionalized resins we have generated shows that EGDMA-IM-DEG [Figure 4(a)] and DVB-DMA [Figure 4(b)] resins showed equilibrium binding of 2.6 and 3.4 times more KAS603 than Amberlite, respectively [Figure 4(c)]. Cur­rently we have obtained binding capacities up to 150 mg algae per g resin. While these resins can be eluted cleanly with the sulfuric acid/methanol reagent so as to generate FAME [Figure 4(d)], they were not designed for this purpose and are potentially susceptible to attack by the strong acid. Future resin designs will need to address the need for chemical stability under harsh conditions.