Alloying of Thorium

Many alloying additions have been attempted for improving mechanical properties and corrosion resistance of thorium. Only few elements (like zirconium and

Table 7.3 Effect of processing on the tensile properties of wrought-annealed and cold worked thorium at room temperature Ref. [13].

Condition”*

Yield

strength

(MPa)

Ultimate tensile strength (MPa)

Elongation

(%)

Gage

length

(mm)

Reduction in area (%)

Iodide

Wrought-annealed

47.5

119

36

50.8

62

Wrought-annealed

77.0

136

44

25.4

60

Bomb reduced

Extruded-annealed rod

149.5

207

51

50.8

74

Extruded-annealed rod

190

237

51

50.8

73

Wrought-annealed rod

181

232

55

35.6

69

Wrought annealed rod

219.8

265

48

50.8

69

Wrought annealed sheet

209

273

52

Cold rolled 37.5% rod

313

337

20

35.6

61

Cold rolled 25% sheet

378

404

11

25.4

39

Cold rolled 50% sheet

424

451

5

25.4

16

a) Note that the materials were in variously processed initial conditions before tensile testing at room temperature.

hafnium) allow extensive solid solubility. However, many reactive elements form intermetallic compounds instead of forming solid solutions. Addition of two known alloying elements, namely, uranium and indium, to thorium improves the mechanical strength of thorium, whereas three elements, namely, zirconium, tita­nium, and niobium, improve corrosion resistance. Thorium-uranium and tho­rium-plutonium alloys provide opportunities for combining fertile and fissile materials to develop potential thorium-based fuel cycles. Table 7.4 summarizes ten­sile properties of Th-U alloys as a function of uranium content. It clearly shows that uranium addition to thorium increases the yield strength and tensile strength; however, it decreases ductility. Thorium-uranium alloys in excess of 50 wt% U can be readily melted and cast. Powder metallurgy techniques can also be used.

Table 7.4 Tensile properties of (bomb-reduced, annealed) Th-U alloys after [2, 5].

Uranium content (%)

Yield strength (MPa)

Tensile strength (MPa)

Elongation

(%)

Reduction in area (%)

Poisson’s

ratio

Unalloyed

134

218

46

50

0.25

1.0

176

265

38

49

0.25

5.1

189

291

37

47

0.24

10.2

207

310

35

44

0.24

20.6

212

328

32

41

0.24

30.9

249

384

28

36

0.23

40.6

266

430

24

34

0.23

51.2

276

445

17

26

0.22

59.1

300

458

11

23

0.22

image612

Figure 7.17 Strain rate versus stress from the creep tests at 600 °C of differently processed Th-9 wt% U alloys Ref. [13].

The creep data of Th-9wt% U alloy are shown in Figure 7.17. The plot shows retention of strengthening due to the mechanical effect at 600 °C.