Susceptibility to Induced Radioactivity

The materials in the reactor can absorb fast/thermal neutrons and undergo reactions that may lead to the production of different radioactive isotopes of the constituent elements of the materials. These reactions can induce radio­activity as these isotopes would decay by emitting gamma rays, beta rays, and alpha rays of different energy levels. While selecting an alloy, we should be concerned about the following factors: (a) quantity of the impurities/alloying elements, (b) abundance of the isotopes and corresponding cross section, (c) half-life of the product nuclide, and (d) the nature of the radiation produced.

If the produced isotope has a short half-life and emit radiation of low energy, it should not be a cause for great concern. However, if the isotope is long-lived and produces radiation of high energy, all precautions must be taken. For

Подпись: Note The development of reduced activation steels comes from the consideration of the induced radioactivity. In the mid-1980s, the international fusion reactor program initiated the development of these steels first in Europe and Japan and later in the United States. The rationale behind developing these materials stems from the easier hands-on maintenance and improved safety of operation requirements that the materials used to build the fusion reactor would not activate when irradiated by neutrons or even if it gets activated may develop only low level of activation and would decay fast. Thus, the program to produce reduced activation steels that would require only shallow burial as opposed to putting them in deep geologic repository was pursued. Researchers found out that replacing or minimizing the amount of molybdenum, niobium, nickel, copper, and nitrogen in the alloy steels would help in developing reduced activation steels. Tungsten, vanadium, and/or tantalum (low activating) have been added to these steels. Table 1.6 shows the nominal compositions of three reduced activation steels. Although the approach has originated in the fusion reactor program, it can be equally applicable to fission reactor systems.

example, the main isotope of iron (Fe56) that accounts for almost 92% of the natural iron forms a stable isotope (Fe57) upon absorbing neutrons. The absorption of neutrons in Fe54 and Fe58 yielding Fe55 (half-life: 2.9 years) and Fe59 (half-life: 47 days) results in activation. However, the impurities or alloy­ing elements cause more induced radioactivity than iron itself. Generally, the test samples irradiated in a reactor are not examined immediately after taking out from the reactor because they remain literally hot and continue to be hot due to the decay heat produced by various reactions even if the fission chain reaction no longer occurs. The Fukushima Daiichi accident in Japan did show the severity of the heat produced due to these decay reactions even after the emergency shutdown of the reactor, leading to very high temperatures (in the absence of proper coolant) and eventually resulting in the cladding breach and perhaps some form of core melting.

Table 1.6 Nominal compositions of reduced activation steels (in wt%, balance Fe).

Steel

Region

C

Si

Mn

Cr

W

V

Ta

N B

JLF-1

Japan

0.1

0.08

0.45

9.0

2.0

0.2

0.07

0.05 —

Eurofer

Europe

0.11

0.05

0.5

8.5

1.0

0.25

0.08

0.03 0.005

9Cr-2WVTa

USA

0.10

0.30

0.40

9.0

2.0

0.25

0.07

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