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14 декабря, 2021
At pressures below 6 GPa, the melting temperatures of Na, Pb, and Pb-Bi(e) increase monotonically with decreasing rate with pressure. The melting temperature of Na increases from 371 K at an atmospheric pressure up to 507-522 K when pressure increases up to 3 GPa37-39; the melting temperature of Pb increases from 600.6 to 795-815 K at the same pressure increase.38,40 For Pb, the rate of the melting temperature increase of 0.0792 KMPa-1 in the pressure range of 15-200 MPa, 0.0671 K per 1 MPa in the range of 0.8-1.2 GPa, and an increase of 5.4 K for the pressure increase from 2 to 3 GPa, were cited in Hofmann.2
Parameter |
Unit |
Na |
Pb |
Pb-Bi(e) |
TM,0 |
K |
371.0 |
600.6 |
398 |
bTu |
KGPa-1 |
59.5 |
71.94 |
46.7 |
CTm |
KGPa-2 |
-3.9 |
-1.546 |
— |
Table 3 Coefficients of the correlation [1] for the pressure dependence of the melting temperatures (in K) of Na, Pb, and Pb-Bi(e) |
The eutectic point of Pb-Bi(e) is shifted to lower Pb contents and higher melting temperature with pressure. The eutectic temperature increases from 398 K at normal atmospheric pressure to ^422 K at pressure 0.75 GPa and to ~-481 K at 1.8 GPa41
In the pressure range of 0.1 MPa-3 GPa, the parabolic function can be used for the description of the pressure dependence of the melting temperatures of Na, Pb, and Pb-Bi(e), (Table 3):
Tm(p) = tm, o + bTM (p — po) + cTm (p — po)2 I1]
The melting temperatures of Na and Pb as functions of pressure up to p = 6 GPa and up to 1.8 GPa for Pb-Bi(e), are presented in Figure 2. At higher pressures, a more complicated behavior of the melting temperatures of the considered metals in the function
of pressure is observed.39,42