Melting Line

At pressures below 6 GPa, the melting temperatures of Na, Pb, and Pb-Bi(e) increase monotonically with decreasing rate with pressure. The melting tempera­ture of Na increases from 371 K at an atmospheric pressure up to 507-522 K when pressure increases up to 3 GPa37-39; the melting temperature of Pb increases from 600.6 to 795-815 K at the same pressure increase.38,40 For Pb, the rate of the melting tempera­ture increase of 0.0792 KMPa-1 in the pressure range of 15-200 MPa, 0.0671 K per 1 MPa in the range of 0.8-1.2 GPa, and an increase of 5.4 K for the pressure increase from 2 to 3 GPa, were cited in Hofmann.2

Parameter

Unit

Na

Pb

Pb-Bi(e)

TM,0

K

371.0

600.6

398

bTu

KGPa-1

59.5

71.94

46.7

CTm

KGPa-2

-3.9

-1.546

Table 3 Coefficients of the correlation [1] for the pressure dependence of the melting temperatures (in K) of Na, Pb, and Pb-Bi(e)

Подпись: Table 2 Characteristic temperatures and temperature ranges of liquid Na, Pb-Bi(e), and Pb at normal atmospheric pressure TM,O (K) DHM,O (kJmol-1) TB,O (K) DHB,O (kJmol-1) TB,O - TM,O (k) Na 371.0 ± 0.1 2.60 ± 0.03 1155 ± 2 97.4 ± 0.1 784 ± 2 Pb-Bi(e) 398 ± 1 8.04 ± 0.06 1927± 16 178 ± 1 1529± 17 Pb 600.6 ± 0.1 4.78 ± 0.03 2021 ± 3 177.9 ± 0.4 1420 ± 4
The eutectic point of Pb-Bi(e) is shifted to lower Pb contents and higher melting temperature with pres­sure. The eutectic temperature increases from 398 K at normal atmospheric pressure to ^422 K at pressure 0.75 GPa and to ~-481 K at 1.8 GPa41

In the pressure range of 0.1 MPa-3 GPa, the para­bolic function can be used for the description of the pressure dependence of the melting temperatures of Na, Pb, and Pb-Bi(e), (Table 3):

Tm(p) = tm, o + bTM (p — po) + cTm (p — po)2 I1]

The melting temperatures of Na and Pb as functions of pressure up to p = 6 GPa and up to 1.8 GPa for Pb-Bi(e), are presented in Figure 2. At higher pres­sures, a more complicated behavior of the melting temperatures of the considered metals in the function

of pressure is observed.39,42