Thermal Conductivity of the Liquid State

Подпись: Table 10 Thermal conductivity (Wm 1K 1) of the actinide metals above room temperature Phase l = a + b x T (K) + c x T2 (K) + d x T 3(K) T (K) References a b c d Th 48.101 0.00336 100-1000 75 U 19.019 0.03256 -1.8235 x10-5 1.0343x10-5 100-100 75 Np 4.18 300 75 Pu a 2.264 0.00696 2.5332 x10-5 100-399 75 p 15.4 399-488 66 g 3.54 0.02 488-596 76 8, 8' 6.94 0.01 596-759 76 e 0.44 0.01 759-913 76 Liquid 16.5 913-1073 76
Only data available for the thermal diffusivity and conductivity of the liquid state of plutonium have been reported. Wittenberg and coworkers77,78 mea­sured the thermal diffusivity (D) from which they derived the thermal conductivity, which is constant in the measured range (973 to 1073 K). As discussed above, the two publications by these authors are not consistent. In the early one,78 Wittenberg gave 0.017-0.021 and 0.022-0.023 cm2 s-1 for the thermal diffusivity in two experiments with different heating

Подпись: La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Figure 22 The variation of l/sT of the actinide (o) and lanthanide (•) metals. The estimated values are indicated by 0.

rates, yielding to l = 5.4 Wm-1 K-1 and 6.3 Wm-1 K-1, respectively. In the later publication,77 Wittenberg reports D = 0.057-0.056 cm2 s-1 for the temperature range 948 to 1073 K, yielding l = (17±1) Wm-1 K-1. This latter value is recommended here.