Radiation Damage Using Ion Beams

G. S. Was

University of Michigan, Ann Arbor, MI, USA R. S. Averback

University of Illinois at Urbana-Champagne, Urbana, IL, USA © 2012 Elsevier Ltd. All rights reserved.

1.07.1

Introduction

195

1.07.2

Motivation for Using Ion Beams to Study Radiation Damage

196

1.07.3

Review of Aspects of Radiation Damage Relevant to Ion Irradiation

197

1.07.3.1

Defect Production

197

1.07.3.2

Primary and Weighted Recoil Spectra

199

1.07.3.3

Damage Morphology

200

1.07.3.4

Damage Rate Effects

202

1.07.4

Contributions of Ion Irradiation to an Understanding of Radiation Effects

204

1.07.4.1

Electron Irradiations

204

1.07.4.1.1

Displacement threshold surfaces

204

1.07.4.1.2

Point defect properties

205

1.07.4.2

Ion Irradiations

206

1.07.4.2.1

The damage function

206

1.07.4.2.2

Freely migrating defects

207

1.07.4.2.3

Alloy stability under ion irradiation

207

1.07.4.2.4

Mechanical properties

209

1.07.4.2.5

Multiple ion beams

209

1.07.4.2.6

Swift ions

209

1.07.4.3

Comparison with Neutrons

211

1.07.5

Advantages and Disadvantages of Irradiations using Various Particle Types

215

1.07.5.1

Electrons

216

1.07.5.2

Heavy Ions

217

1.07.5.3

Light Ions

219

1.07.6

Practical Considerations for Radiation Damage Using Ion Beams

219

References

221

Abbreviations

AES

Auger electron spectroscopy

APT

Atom probe tomography

bcc

Body-centered cubic

BWR

Boiling water reactor

dpa

Displacements per atom

fcc

Face-centered cubic

FMD

Freely migrating defect

FP

Frenkel pair

IASCC

Irradiation assisted stress corrosion cracking

IGSCC

Intergranular stress corrosion cracking

LWR

Light water reactor

MD

Molecular dynamics

NRT

Norgett-Robinson-Torrens

NWC

Normal water chemistry

PKA

Primary knock-on atom

RCS

Recoil collision sequence

RIS

Radiation induced segregation

SCC

Stress corrosion cracking

STEM/EDS

Scanning transmission electron

microscopy/energy dispersive

spectrometry

TEM

Transmission electron microscopy

1.07.1 Introduction

Radiation effects research has been conducted using a variety of energetic particles: neutrons, electrons, protons, He ions, and heavy ions. Energetic ions can be used to understand the effects of neutron irradiation on reactor components, and interest in this application of ion irradiation has grown in recent years for several reasons including the avoidance of high residual radioactivity and the decline of neutron sources for materials irradiation. The damage state and microstructure resulting from ion irradiation, and thus the degree to which ion irradiation emulates neutron irradiation, depend upon the particle type and the damage rate. This chapter will begin with a summary of the motivation for using ion irradiation for radiation damage studies, followed by a brief review of radia­tion damage relevant to charged particles. The contri­bution of ion irradiation to our understanding of radiation damage will be presented next, followed by an account of the advantages and disadvantages of the various ion types for conducting radiation damage studies, and wrapping up with a consideration of prac­tical issues in ion irradiation experiments.