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Considering the characteristics of nuclear data, the time needed for the investigations (several days) should match the half-life of the radionuclides. For measurements outside the equipment wall, gamma-emitting radionuclides with relatively high energy (>300 keV) are suitable. Radionuclides emitting a high number of gamma quantums per decay are advantageous; because of their higher count rate, lower activity is necessary for the investigations (see the role of the a factor in Eq. (11.3)). Certainly an important consideration when selecting the radionuclide is simplicity of its preparation, which should take place in the research reactor through the (n, Y) nuclear reaction, favorably with a high activity yield (as discussed in Section 8.5.2).
In addition to nuclear data, physical and chemical features will determine which radionuclides can be selected for a given tracer study. Radionuclides most frequently used for industrial tracer studies are summarized in Table 11.1.
In the preparatory phase of the tracer study, at the preparation of the radionuclide, and during the investigation, rules governing the handling of radioisotopes must be complied with. The fate of the radioactive isotopes used for industrial tracer studies is important to define in advance and solve in an authorized manner.
The simplest way is to store the material labeled with relatively short-lived radionuclides in a well-separated place until its radioactivity decays below the
Table 11.1 |
Radionuclides Used for Industrial Tracer Studies |
||
Radioisotope |
Half-Life |
Gamma Photon Energy (keV) |
Application Field |
Na-24 |
15 h |
1370 |
For labeling solid grains |
K-42 |
12 h |
1520 |
For labeling solid grains |
Sc-46 |
84 days |
890 |
For labeling solid grains, e. g., in silicate industry |
Cr-51 |
28 days |
323 |
For labeling metals and alloys |
Mn-56 |
2.6 h |
1360 |
For labeling metals and alloys |
Fe-59 |
45 days |
1100 |
For labeling ferrous metals |
Cu-64 |
13 h |
510 |
For labeling metals and alloys |
Zn-65 |
245 days |
1110 |
For labeling metals and alloys |
Br-82 |
36 h |
780 |
For labeling stream waters |
I-131 |
8 days |
360 |
For halogenation |
Rb-86 |
19 days |
1080 |
For labeling solid grains |
Ag-110m |
253 days |
660 |
For labeling metals and alloys |
La-140 |
40 h |
1600 |
For labeling solid grains, e. g., in silicate industry |
Au-198 |
2.7 days |
412 |
For labeling solid grains as colloid |
Hg-203 |
47 days |
279 |
For mercury electrolysis as metal |
Kr-85 |
10 years |
510 |
For labeling gases |
exempted activity level. Storing time can be considerably reduced if the labeled material is diluted during the technological processes or is artificially diluted after the study. In such cases, the exempted radioactive concentration will be the precondition of the release. For instance, the dilution rate of a radioactive-labeled component that is introduced into a huge storing container with a great volume of nonradioactive material can even grant an exemption from separated storage.