Heating values of various kinds of biomass

Table 2.4.1 gives the data for moisture content, organic matter content, ash content, and heating value of representative types of biomass.

Table 2.4.1. Typical analyses and heating values of representative types of biomass, coal, and peat.

Category

Biomass

Moisture

content*

[wt%]

Organic matter [dry wt%]

Ash**

[wt%]

High heating value

[MJ/dry-kg]

Waste

Cattle manure

20—70

76.5

23.5

13.4

Activated biosolids

90—97

76.5

23.5

18.3

Refuse-derived

fuel(RDF)

15—30

86.1

13.9

12.7

Sawdust

15—60

99.0

1.0

20.5

Herbaceous

Sweet sorghum

20—70

91.0

9.0

17.6

plant

Switch grass

30—70

89.9

10.1

18.0

Aquatic plant

Giant brown kelp

85—97

54.2

45.8

10.3

Water hyacinth

85—97

77.3

22.7

16.0

Woody plant

Eucalyptus

30—60

97.6

2.4

18.7

Hybrid poplar

30—60

99.0

1.0

19.5

Sycamore

30—60

99.8

0.2

21.0

Derivatives

Paper

3—13

94.0

6.0

17.6

Pine bark

5—30

97.1

2.9

20.1

Rice straw

5—15

80.8

19.2

15.2

Coal

Illinois bituminous

5—10

91.3

8.7

28.3

Peat

Reed sedge

70 —90

92.3

7.7

20.8

* Moisture content is determined from the weight loss after drying for at 105°C under

atmospheric pressure.

** Ash content is determined from the weight of residue (metal oxides) left after heating at about 800°C.

Moisture content differs considerably depending on the kind of biomass, for example, 3% in paper and 98% in sludge. With most biomass types, water content exceeding two-thirds makes the available heat negative (-). Therefore, even if the heating value of the biomass itself is high, if it has a high moisture content in its natural state, it is not suitable for combustion. For example, water hyacinth and sewage sludge have high heating values, when they are dried, but moisture content is about 95% at the sampling, and they are unsuitable for combustion actually.

Total organic matter is left when the ash content subtract from total dry matter. Because the value of ash as energy is zero, a large amount of organic matter means a higher heating value, which is desirable as an energy source. Additionally, organic substances have different heating values depending on the kinds and ratios of their constituent elements (see 2.3 Biomass Composition). Table 2.4.2 presents the elemental analysis results and heating values of representative biomass types and other organic fuels. Because biomass contains more oxygen and less carbon and hydrogen than coal or petroleum, it has a lower heating value per unit weight. Woody and herbaceous biomass types have carbon contents of 45%-50% and hydrogen contents of 5%-6%, giving them an H:C molar ratio of about 2, with little variation. This is because they are affected by their composition, the main components of which are cellulose and lignin.

Table 2.4.2. Typical elemental compositions and heating values of representative types of biomass, coal, and peat.

^»"»-^Energy source

Cellulos

e

Pine

Giant brown kelp

Water

hyacinth

Livestoc k waste

RDF

Sludg

e

Peat

Bitume

n

Carbon [wt%]

44.44

51.8

27.65

41.1

35.1

41.2

43.75

52.8

69.0

Hydrogen [wt%]

6.22

6.3

3.73

5.29

5.3

5.5

6.24

5.45

5.4

Oxygen [wt%]

49.34

41.3

28.16

28.84

33.2

38.7

19.35

31.24

14.3

Nitrogen [wt%]

0.1

1.22

1.96

2.5

0.5

3.16

2.54

1.6

Sulfur [wt%]

0

0.34

0.41

0.4

0.2

0.97

0.23

1.0

Ash [wt%]

0.5

38.9

22.4

23.5

13.9

26.53

7.74

8.7

Heating value [MJ/dry-kg]

17.51

21.24

10.01

16.00

13.37

12.67

19.86

20.79

28.28

With respect to moisture content and other properties, elemental ana in dried condition.

ysis results were all obtained