Terrestrial Biofuels

For some applications, biomass as it is produced in solar energy conversion may be used as such. This applies, for instance, to the generation of electricity, which in turn may be used for electrical traction. However, diesel or Otto motors or fuel cells need the use of specific biochemicals (transport biofuels) such as specific alcohols and acylesters, as discussed in Chap. 1. This has an impact on the efficiency of solar conversion. Only a part of the biomass originating in solar energy conversion can be turned into such chemicals. It may be that part of the biomass that cannot be con-

Inso­

lation

(MJ/

day m2)

Crop under good condi­tions (unless otherwise indicated)

Yield of biomass ha~1 (Mg dry weight/ year); above­ground except for sugar beet

Energy con­tent biomass (lower heat­ing value in MJ/kg dry weight)

Correction factor for fos­sil fuel input (MJ in crop — MJ fossil fuel input/MJ in crop)

Solar energy conversion efficiency (%)

19

Sugar cane (average)

36.8

(Kheshgi et al. 2000)

17.5

0.97

(Dias de Oliveira et al. 2005)

0.9

19

Oil palm

20

(fruit bunches)

31.7

0.95

(Reijnders and Huijbregts 2003)

0.87

19

Eucalyptus

10-20

19

0.9 (estimate)

0.25-0.50

14

Wheat

10-11

17.5

0.8

(von Blottnitz and Curran 2007)

0.27-0.30

14

Switchgrass

10-15

17.5

0.95 (estimate)

0.32-0.48

14

Sugar beet

20

17

0.9

(von Blottnitz and Curran 2007)

0.62

14

Corn

17-18

17.5

0.8

(von Blottnitz and Curran 2007)

0.46-0.49

14

Rapeseed/

Canola

4-5

21.8

0.9

(Zahetal. 2007)

0.15

14

Miscanthus

10-13

17.5

0.98

(Lewandowski and Schmidt 2006)

0.34-0.44

14

Poplar

9.5

(Kheshgi et al. 2000)

19.8

0.98

0.36

14

Wood grown sustainably in Western Russia (Nabuurs and Lioubimov 2000)

1.4

19.8

0.95

(Reijnders and Huijbregts 2003)

0.05

verted into the biochemicals needed is used to power the production from biomass of specific biochemicals. It may also be that a part of the original biomass emerges from processing as waste. Furthermore, in many processes generating biochemicals from biomass, there is an input of fossil fuels that is to be taken into account when determining overall conversion efficiencies. Figure 2.1 gives estimated efficiencies for some conversions of biomass into transport biofuels.

Table 2.2 shows solar conversion efficiencies for a number of biofuels from ter­restrial plants. In this case, the allocation has been done on the basis of energy content of marketable products.

The efficiencies in the last column of Table 2.2 are typically lower than the effi­ciencies shown in Table 2.1. Most of them are below 0.2%. For ethanol from Euro­pean wheat starch, the efficiency is 0.024-0.03%, and for biodiesel from European rapeseed, it is approximately 0.034%. Apart from Jatropha, which has quite an un­certain conversion efficiency, the best efficiency in Table 2.2 is for ethanol from switchgrass, with ethanol from sugar cane coming second. However, it was assumed in this table that in the case of sugar cane, only sugar is to be converted into ethanol. If also a substantial part of the lignocellulosic aboveground biomass of sugar cane is converted into ethanol, sugar cane may as efficient as or better than switchgrass.

Crop/Process

Insolation (MJday-1 /m2)

Fuel

Yield of biofuel ha 1

(Mg/year)

Heat of combus­tion of biofuel (MJ/kg)

MJ biofuel — MJ fossil fuel input/MJ biofuel

MJ biofuel — MJ fossil/MJ crop

Solar energy conversion effi­ciency (%)

Oil palm

19

Palm kernel oil

40

0.7-0.9 (Reijnders and Huijbregts 2008a; de Vries 2008)

— 0.15

(Reijnders 2008)

Sugar cane

19

Ethanol

26.4

0.16 (Kheshgi et al. 2000)

Wheat (Europe)

14

Ethanol

1.65 (from starch)

26.4

0.2-0.25 (Somerville 2007)

0.024-0.03

Switchgrass to be processed to ethanol

14

Ethanol

15

26.4

0.25 (Fleming et al. 2006; Champagne 2007)

0.2

Jatropha

19

Oil

0.65-5 (Fairless 2007; van Eijck and Romijn 2008)

40

0.9 or lower

0.035-< 0.26

Switchgrass

14

Fischer-Tropsch

diesel

15

44

0.14 (Somerville 2007)

0.18

Wood from trees

14

Methanol gen­erated by dry distillation

0.04 (Reinharz 1985)

19.8

0.0015

Wood (Europe)

14

Fischer-Tropsch

diesel

1.4

44

0.12-0.33 (Huber et al. 2006)

0.014-0.039

Rapeseed

14

Biodiesel

1.15 (oil, before transesterification)

0.4 (Reijnders and Huijbregts 2008b)

0.034

Table 2.2 Efficiency of solar energy conversion into specific biochemicals, when corrected for fossil fuel inputs and when allocation is based on prices

60 2 Energy Balance