Direct Liquefaction

Thermal conversion of biomass to liquids can proceed via non-pyrolytic processes, in which the feedstock is directly heated in a liquid medium that may or may not interact with the biomass (Cheng et al. 2010; Klass 1998; Titirici et al. 2007). Low temperature and atmospheric pressure in the presence of a solvent with acidic or basic catalysts can be used, but these solvents have to be recycled, rendering the process energetically and financially costly. The use of higher temperatures and pressures in water have shown promising results and recently an increase of inter­est regarding hot-compressed or sub-/supercritical water technologies (hydrother­mal technologies) for biomass conversion has appeared (Peterson et al. 2008). Hydrothermal processing can be divided into three main regions, namely: lique­faction, catalytic gasification and high-temperature gasification, depending on the

Table 7.2 Product yields resulting from thermochemical conversion of Pinus, Eucalyptus, and Acacia species

Lignocellulose source

Conversion technologies

Yields (wt.%)

Reference

Eucalyptus species

Gasification

S: 6-15

Pindoria et al. (1998)

G:86-88

Fast pyrolysis

L:53-76

Kumar et al. (2010)

S: 13-20 G: 11-25

Oasmaa et al. (2010)

Slow pyrolysis

L: 46-50

Pimenta et al. (1998)

S: 30-38 G:16-20

Kumar et al. (2010)

Combustion

S: 24-44

Suarez et al. (2010)

Liquefaction

L:50-90

Zhang et al. (2012)

Liquefaction

L: 51 daf, wt.% S: 41 daf, wt.% G: 8 daf, wt.%

Sugano et al. (2008)

Acacia species

Vacuum pyrolysis

L: 27

Uras et al. (2012)

S: 38

G: 35

Slow pyrolysis

C:30-34

El-Juhany et al. (2003)

Pinus species

Gasification

L:40-66 G:14-40 S: ~ 20

Sunetal. (2011)

Flash pyrolysis

L:65-75 S: 5-18 G: 5-20

Wagenaar et al. (1993)

Slow pyrolysis

L:21-30 S: 23-36 G:11-23

Sensoz and Can (2002)

Supercritical

G: ~40

Kersten et al. (2006)

Flash pyrolysis

L: 50

Bhattacharya et al. (2009)

S: 19

G: 31

L liquid, S solid, G gas

temperature and pressure conditions (Klingler and Vogel 2010). The production of biocrude, aqueous organics, combustible gases (H2, CO, CO2, CH4) and light hydrocarbons is expected.