SYNTHESIS OF ETHENYLENE BRIDGED PERIODIC MESOPOROUS ORGANOSILICA (FIGURE 1; PATHWAY A)

In a typical synthesis, reported by our group [45], a total amount of 1.00 g of P123 was placed in a flask and 47.80 mL of distilled H2O, 3.42 mL con­centrated HCl and 2.45 mL 1-butanol were added. The solution was stirred for 1.5 h at room temperature and subsequently 1.86 mL of E-BTSE was added to the mixture. Next, the mixture was vigorously stirred at 35 °C. After 4 h, the temperature was raised to 90 °C and aged for 16 h. After­wards, the mixture was left to cool down, and the white solid was filtered and washed with acetone and distilled water. Finally, P123 was removed via Soxhlet extraction with acetone for 5 h. The white solid, denoted as EP, was dried at 120 °C under vacuum (~0.1 Pa).