HYDROGEN PARTIAL PRESSURE

Hydrogen partial pressure affects significantly the hydrotreating reactions as well as the catalyst deactivation. The catalyst deactivation rate is inverse proportional to the hydrogen partial pressure and to hydrogen feed-rate. However high hydrogen partial pressures correspond to high operation­al costs, which rise even higher for high olefinic feedstocks that exhibit higher hydrogen consumption due to the saturation reactions. Therefore hydrogen partial pressure should be balanced with the catalyst activity and catalyst life expectancy in order to optimize the overall process.

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FIGURE 5: Catalyst comparison based on gasoline and diesel yields for WCO hydrotreating [8]. (Reprinted from Fuel, 93, S. Bezergianni, A. Kalogianni, A. Dimitriadis, Catalyst evaluation for waste cooking oil hydroprocessing, 638-641, 2012, with permission from Elsevier).