Chemical hydrolysis

Whitin chemical hydrolysis, acid hydrolysis is the most used and it can be performed with several types of acids, including sulphurous, sulphuric, hydrochloric, hydrofluoric, phosphoric, nitric and formic acid. While processes involving concentrated acids are usually operated at low temperatures, the large amount of acids required may result in problems associated with equipment corrosion and energy demand for acid recovery. These processes typically involve the use of 60-90% concentrated sulfuric acid. The primary advantage of the concentrated acid process in realtion to diluted acid hydrolysis is the high sugar recovery efficiency, which can be on the order of 90% for both xylose and glucose. Concentrated acid hydrolysis disrupts the hydrogen bonds between cellulose chains, converting it into a completely amorphous state [8].

On the other hand, during dilute acid hydrolysis temperatures of 200-240°C at 1.5% acid concentrations are required to hydrolyze the crystalline cellulose. Besides that, pressures of 15 psi to 75 psi, and reaction time in the range of 30 min to 2 h are employed. During this conditions degradation of monomeric sugars into toxic compounds and other non-desired products are inevitable [9]. The main advantage of dilute acid hydrolysis in comparison to concentrated acid hydrolysis is the relatively low acid consumption. However, high temperatures required to achieve acceptable rates of conversion of cellulose to glucose results in equipment corrosion [4].