Characteristics of textile wastewater

The textile industry consumes the largest portion of the colorant available in the world market. Due to the high customer demand, more than 100,000 commercial dyes exist in the market causing more than 700,000 tonnes of dyes to be produced annually (McMullan et al., 2001; Pearce et al., 2003). The result is a very high production of colored wastewater. The characteristics of textile wastewater (either quantitatively or qualitatively) vary greatly depending on the type of raw materials, chemicals, techniques or specific process operations at the mill, the equipment used and the production design of the textile processes (Bisschops and Spanjers, 2003; Dos Santos et al., 2006).

The textile industry consumes huge amounts of water in its wet processes. The average wastewater generation from a dyeing facility is estimated between 3800 and 7600 million m3 per day. Desizing, scouring, bleaching, mercerizing and dyeing are the common wet textile process operations. Among these, the mercerizing and dyeing processes consume the biggest specific volumes of water with a water usage of 230-310 L/kg and 8-300 L/kg of textile processed, respectively (Dos Santos et al. 2007).

Due to inefficiency of the textile processing activities, only 10% of the chemicals in the pre­treatment and dyes in dyeing operations remain on the fabric. In other words, about 90% of chemical substances will be discharged as textile effluent (IPPC, 2003). Others have reported that between 50 and 95% of the dyes are fixed on the fiber while the remainder is discarded in the subsequent textile-washing operations (EPA, 1997; Trovaslet et al., 2007). The amount of dye lost into the wastewater depends upon the type of dyestuff used, as well as the methods and application routes of the textile processing operation. Additionally, it depends on the intended color intensity that is required for each particular design (Willmott et al., 1998).

Textile wastewater is characterized with high chemical and biochemical oxygen demand, suspended solids, high values of conductivity and turbidity and intense color. This is caused by the presence of dye residues or intermediates and auxiliary chemicals added in the many stages in textile processing (Mohan et al., 2007a; Miranda et al., 2009). Textile processes with natural fibers generate higher pollution load as compared to synthetic fibers mainly due to the use of pesticides for preservation of the natural fibers (Correia et al., 1994).

Textile dyeing wastewater is also characterized by high salt content, which also imposes potential environmental problems. Typical cotton batch dyeing operations use quantities of salt that range from 20 to 80% of the weight of goods dyed, with common concentrations between 2,000 mg/L and 3,000 mg/L. Sodium chloride and sodium sulfate constitute the majority of the total salts used. Magnesium chloride and potassium chloride are used as raw materials in lower concentrations (EPA, 1997).

Common characteristics of textile wastewater from cotton textile wet processing for different processing categories are shown in Table 1. The highest concentration of organic pollutants (in terms of COD) is generated from bleaching while the highest concentration of total solids comes from the desizing process. The highest concentration of color, ranging from 1450-4750 ADMI, is generated from the dyeing process (Bisschops and Spanjers, 2003;

Dos Santos et al., 2007). Metals such as copper, cadmium, chromium, nickel and zinc are also found in textile effluents, as they are the functional groups that form the integral part of the dye molecule (IPPC, 2003).