Effect of competitive ions on the sorption of lanthanides

The percentage removal of lanthanides under the presence of common ions (Ca2+, Mg2+, Na+ and K+) at different concentrations 50, 100 and 200 mg-dm-3 is shown in Fig. 10. From this figure, the remarkable decrease of sorption capacity of lanthanides was not observed. Even when the concentrations of common ions are 200 mg-dm-3, the percentage removal of light REE (LREE) such as La or Ce decreased slightly (2-3%), whereas the removal decreased about 5% for heavy REE (HREE) such as Yb or Lu. This implies that the shell biomass can be an efficient adsorbent for lanthanides in aqueous environment such as seawater, although it requires further investigations to apply the shell biomass to use as an adsorbent for lanthanides more practically.

image040

Figure 10. Effect of common ions (Ca2+, Mg2+, Na+ and K+) on the removal efficiency of lanthanides using ground original sample.