Conditioning: Target L gas

Two different L gas target properties have been described. Because of their basic constitutions, one bio-methane mixture is conditioned with air and the other is conditioned with a combination of air and LPG.

Table 14 shows a summary of the admixtures with which a target calorific value-oriented mixture for the low calorific base gas property can be achieved.

In the case of simple air addition, particular attention should be paid to compliance with the maximum O2 volume fraction. This should not exceed 3 % vol. in dry networks according to DVGW worksheet G 260. This quantity is reached when adding pure air to the processed biogas, at an admixture of 15 vol -% of air. In the low caloric L gases (e. g. Weser Ems gas), this limit is never reached.

Furthermore, a minimum air addition may also be necessary, in order to achieve the required Wobbe Index according to DVGW worksheet G 260.

Table 15 shows the minimum air addition for the individual processing grades of methane to achieve an L gas compliant Wobbe Index of under 13.0 kWh/m3 (NTP).

Air admixtures to attain the target calorific value + / — 2%

Weser Ems L Gas

Methane concentration after

processing

in vol -%

Hs, n = 9,653 — 10,047 kWh/m3

Air admixture

in Vol.-%

94,0

3,6 — 7,7

96,0

5,8 — 10,0

98,0

8,0 — 12,3

99,5

9,7 — 14,0

Table 14. Air additions to the H gas properties under investigation

Methane

in

Biogas

Methane

in

admixture

CO2

in

admixture

Air to the Biogas

O2

in

admixture

Calorific

value

Wobbe

Index

rel.

Density

in Vol.-%

in Vol.-%

in Vol.-%

in Vol.-%

in Vol.-%

in kWh/m3

in kWh/m3

94,000

92,429

5,506

1,700

0,645

10,226

12,999

0,619

96,000

91,778

3,442

4,600

1,208

10,154

12,996

0,611

98,000

91,163

1,488

7,500

1,741

10,086

12,993

0,603

99,500

90,702

0,091

9,700

2,126

10,035

12,988

0,597

Table 15. Minimum quantity of air to attain L gas specification

For the high-caloric L gas mixtures (target properties according to Holland II L gas) the processed biogas is conditioned with air and LPG. Table 16 shows the correlating LPG-air additions, to reach the calorific value range (+ / -2%).

The gray-shaded areas show where a compliant combination of air and LPG additions is impossible. With increasing LPG additions, the necessary addition of air is limited by the maximum O2 volume fraction of 3 %. If too little LPG is added, only the lower calorific value range can be covered. The broadest coverage of the calorific value range lies in between and is marked by the wider bandwidth of air additions.

in the Vol -%

0

2.

4

6

8

Holland II

Hs, n =

9,996 — 10,404 kWh/m3

94

2

4

4

7

7

10

10

14

14

16

96

5

5

7

9

9

12

12

16

16

16

98

10

11

11

15

14

16

99,5

12

13

13

15

16

16

Methane concentration

LPG — addition [Vol -%]

Table 16. Air addition, depending on the addition of LPG and methane concentration