Conditioning: Target H gas

The table 11 shows the determined rates of admixture for LPG to attain the appropriate target calorific value range. With the LPG quantities shown, the respective initial concentrations of methane, the entire calorific value range of the respective base gas quality is covered, with some restrictions.

LPG mixing rates to achieve the target calorific value + / — 2%

North Sea I H gas

Methane

concentration after

Hs, n =

11,956 — 12,444 kWh/m3

processing in vol -%

LPG

in Vol.-%

94,0

9,4 — 12,6

96,0

8,1 — 11,3

98,0

6,8 — 9,9

99,5

5,8 — 8,9

Restriction of the lower calorific value range by high processing levels

Table 11. Air and LPG additions of the investigated H gas properties

For the practical implementation of the listed quantities of the LPG admixtures, limits as given in Table 12 are to be observed, in accordance with the requirements presented on the need for the use and applicability of SGERG88 and AGA8 procedures and the resulting maximum admixture quantities according to Table 12. Due to these limits, defined in DVGW G 486-B2, it will not be possible in every case to reach the upper calorific value range at higher pressures. In addition, the availability of appropriate measuring technology for higher liquid gas fractions is limited. At the very high degrees of methane processing, there are limitations on attaining the lower calorific value range, since when processing to 99.5 Vol -% methane, an H gas with a calorific value of 11.009 kWh / m3 results.

Descriptor

Unit

Limit according to G 486 supplementary sheet 2 Appendix B p> 100 bar

Limit according to G 486 supplementary sheet 2 Appendix B p> 100 bar

Propane

xc3H8

mol.-%

3,5

6.

Butane

xc4H10

mol.-%

1,5

1,5

Table 12. Limits according to DVGW G 486 supplementary sheet 2 appendix B

Table 13 shows the maximum possible, compliant LPG admixture, a propane / butane mixture of 95 / 5 Mass.-%. As a result, it is clear that processing to a maximum methane content of 99.5% vol. with the maximum permissible LPG admixtures, a calorific value of maximum 11,361 kWh/ m3 (NTP) is possible at pressures above 100 bar, and a maximum of 12,075 kWh/m3 (NTP) at pressures below 100 bar.

image233

Figure 14 shows the admixture required to achieve the corresponding H gas properties. The limits on the maximum concentration of propane are also shown according to DVGW regulations G 486 supplementary sheet 2 a ppendix B. Admixtures to achieve the properties of North Sea I / North Sea II H gas are, based upon all levels of methane processing, above the limits. A compliant mixture is not possible in this case, or needs to be tested on an individual basis.

image234

96 98

Methankonzentration [Vol.-%]

Fig. 14. LPG quantities necessary to achieve the target calorific value

In order to achieve higher calorific values, alternative conditioning measures can be employed. For example, ready-made mixtures with customized propane / butane ratios can be used for conditioning. This can increase the calorific value, but technical and physical effects, such as condensation behaviour, methane number and k-number deviations need to be considered.