Odlare et al. (2008) have not found significant change in the pH after 4-year-long biogas residue application rate. The pH of soils were 5.6 and 5.7 in the control and biogas residue treated samples, respectively. Similar results were reported by Fuchs & Schleiss (2008), because they have found an enhance of soil pH for about % unit after harvesting of maize. Because of the alkaline pH of digestates, an increase of the soil pH should be supposed. However, digestate might contain various acidic compounds (e. g. gallic acid). The polycondensation, connection to organic and inorganic colloids and transformation of these acids can have an effect also on the soil chemical properties and finally the decrease of soil pH (Tombacz et al., 1998, 1999), more particularly at the soils with high organic and inorganic colloid contents. Therefore the regular monitoring of soil pH is necessary in case of long-term digestate application.