Hua Song

RTI International USA

1. Introduction

Along with the maturity of the production technology (i. e., fermentation) for a long history, bioethanol has become one of the most significant chemicals and energy carriers in large quantity derived from biomass. Although ethanol production from non-food resources remains challengeable for scientists, how to utilize ethanol in an efficient and economical way opens more space for all researchers both from industry and academia to play with.

Hydrogen is likely to play an important role in the energy portfolio of the future due to its high gravimetric energy density. Especially when it is used in fuel cells, it is an ideal energy carrier that can offer clean and efficient power generation. In the United States, ~95 % of hydrogen is produced using a steam reforming process [1]. Over 50% of world’s hydrogen production relies on natural gas as the feedstock [2]. As the concern for a sustainable energy strategy grows, replacing natural gas and other fossil fuels with renewable sources is gaining new urgency. In this context, producing hydrogen from bio-derived liquids such as bio-ethanol has emerged as a promising technology due to the low toxicity, ease of handling and the availability from many different renewable sources (e. g., sugar cane, switchgrass, algae) that ethanol has to offer. An added advantage of producing hydrogen from bio­derived liquids is that it is quite suitable for a distributed production strategy.

This chapter is aimed to provide a big overview of the current technologies for catalytic hydrogen production from bioethanol while focusing the discussion on the hydrogen production through steam reforming of bioethanol over non-precious metal based catalysts, more specifically, cobalt-based catalysts. By combing the work performed at the author’ laboratories, this chapter will also provide the professional insights on the future development direction of such technologies. Through the estimated economic analysis of this process simulated at industrial scale, the ways of final commercialization of the developed catalyst system specially tailored for central and distributed hydrogen production from steam reforming of bioethanol will be suggested.