Thixotropic fluids

Thixotropic fluids are generally dispersions, which when they are at rest construct an intermolecular system of forces and turn the fluid into a solid, thus, increasing the viscosity. In order to overcome these forces and make the fluid turn into a liquid and which may flow, an external energy strong enough to break the binding forces is needed. Thus, as above a yield stress is needed. Once the structures are broken, the viscosity is reduced when stirred until it receives its lowest possible value for a constant shear rate (Schramm, 2000). In opposite to pseudoplastic and dilatant fluids, the viscosity of thixotrpic fluids is time dependent: once the stirring has ended and the fluid is at rest, the structure will be rebuilt. This will inform about the fluid possibilities of being reconstructed. Wastewater and sewage sludge can be examples of fluids with thixotropic behaviour (Seyssieq & Ferasse, 2003) as well as paints and soap.

1.3 Rheological mathematical models

There are several rheological mathematical models applied on rheograms in order to transform them to information on fluid rheological behaviour. For non-Newtonian fluids the three models presented below are mostly applied (Seyssiecq & Ferasse, 2003).