Category Archives: Fast Reactor Safety. (Nuclear science. and technology)

Sodium Hammer Effects

After the absorption of strain energy by the vessel, the remainder of the available energy is, in part, thermal energy (the core fuel is still considerably hotter than the surrounding sodium) and, in part, kinetic energy (the fuel particles are still moving outwards). The kinetic energy would be directed upward by the unruptured walls, while the thermal energy would be depos­ited in the sodium above the core thus vaporizing some of it. Both the kinetic energy and the sodium vaporization would combine to accelerate the sodium above the core upward toward the vessel plug.

The upward acceleration is therefore achieved by both direct momentum transfer and by further flashing of sodium as fuel particles come into contact with it. The sodium slug or hammer would eventually come to rest in contact with the vessel plug, lifting it against its restraint system. The stretching of this restraint system could allow sodium to egress from the vessel after the accident.

Basic Mathematical Model

The transfer of heat through any material is governed by the heat balance equation:

qc dT/dt = к V2T + H (1.18)

where H is the heat production term. This, like Eq. (1.3), is also time and space dependent.

image009Fig. 1.6. Schematic representation of the thermal distribution through a cross section of a cylindrical fuel pin.

Considering a cylindrical fuel pin in which heat is produced (Fig. 1.6), Eq. (1.18) can be used to derive the average fuel temperature in the follow­ing way. In the radially symmetrical pin

Подпись: (1.19)qc dT/dt = аф + k[(d2T/dr2) + r-‘(dT/dr)]

and by defining a volume-averaged fuel temperature and volume-averaged flux (or power) as

T = (2л/A) f Tr dr and ф = (2л/A) f фг dr (1.20)

Jo Jo

where

A = 2л r dr

J 0

Equation (1.18) becomes

Aoc(df/dt) = афА + 2лкЯ(дТ/дг)лШ (1.21)

By now assuming that

(дТ/дг) ]atiJ = (TBUl[~ Tc)/A

we have

Подпись: (1.22)me df/dt = а’ф — (2л Rk/A)(TBai{ — Tc)

Подпись: Alternatively, image013 Подпись: (1.23) (1.24)

and defining the heat-transfer coefficient h = 2лЯк/A, the average fuel temperature is given by

Now the heat-transfer coefficient h’ must include not only an allowance h for the film drop heat transfer between the surface temperature reurf and the coolant temperature Te as before, but also an allowance for conduction between the point of average fuel temperature T and the surface of the fuel. So

1 /К = (1 /h) + (/%лк) (1.25)

This adjustment is made so that Eq. (1.24) enables Г to be directly calculated whereas using Eq. (1.23) would have required an additional equation to obtain ГзигГ from f and Tc. Thus for the average fuel temperature, the equation becomes (Fig 1.7)

m[C{(dTf/dt) = аф— h^Tt — Tc) (1-26)

In a similar manner the average coolant temperature equation becomes

mcec(dTc/dt) = ht(Tt — Tc) + hB(Ts — Tc) — mcecvc(dTJdz) (1.27)

image015

Fig. 1.7. Thermal distribution through a cross section of a cylindrical fuel pin and cladding.

where the last term accounts for the transfer of heat as the fluid moves down the channel with velocity v0. Average temperatures of any other material such as structural components in the core can be established in an exactly similar manner; i. e.,

mBc3(dTJdt) = Ьф — hs(Ts — T0) (1.28)

where in this case Ьф accounts for any direct у heating of the structure. Equation (1.27) accounts for heat deposited in the coolant from the fuel element h((Tt — Tc) and from the structural material hs{Ts — Tc).

1.3.1.1 Steady-State Temperatures

With all time derivative terms set to zero, by adding the steady-state temperatures of this system (fuel, coolant, and structure) we can obtain

Tc = Tc. m + [(a + b) J*Ф dz]lmcccvc

(1.30)

Tf = Tc + аф/hf

(1.31)

TS = TC + Ьф/hg

(1.32)

Thus one can obtain a complete distribution of temperatures as a function of z if the heat input distribution ф(г) and the coolant inlet temperature Tc. are known.

It is worth noting that the inlet temperature is effectively a base tempera­ture for the system. Any increase in coolant inlet temperature is reflected by an identical increase in all the other temperatures in the steady state—if the power is retained constant. In practice, we shall see in the next section that, in the absence of external controls, the power ф will also change as a function of temperature because of feedback reactivity changes. However this change of power is a secondary effect.

Boolean Quantization

By defining an algebra to quantize each logic gate, we can calculate a probability for the final consequence in a single-failure fault tree from the initial probabilities of each causal event.

The AND gate is defined as a multiplicative operator; with inputs Х1г X2 Xn, the output of the AND gate is the product XxX2- ■ — Xn.

The OR gate however is defined as an additive operator; with inputs Хг, X2 Xn, the output of the OR gate is the sum xt + x% л— + xn.

The INHIBIT gate is also defined multiplicatively; if an input Xn has a condition W then the output of the INHIBIT gate is the product WXn.

Figure 1.32 shows the Boolean expression for each gate. The INHIBIT and AND gates are clearly very closely related. In many cases the fault tree

OR gate

image063

Подпись: AND gate Output event = A A = X, andX2and X„ =X, X2 X„
image065

Output event — В B=X, or X2or — Xn

Подпись: INHIBIT gate Output event - C C = X„ multiplied by W --шп
image067

=xt + x2 + ■■■ + xn

Input event

Fig. 1.32. Boolean quantization of AND, OR, and INHIBIT gates.

can be expanded by the use of either interchangeably; it depends on whether the analyst wishes to probe the reasons for the INHIBIT conditional modifier.

Figure 1.33 shows a representative section of a fault tree with inputs Xx, X2, and X3. The final output event may be quantized by evaluating each gate output thus:

Ax = BXA2 B2 = Xx X2 B3 = Xx + X2

Bx = X2+ B2 a2 = B3X3 (1.60)

Then the overall output is given by

Output = AX = BxA2 = (X2 + B2)(B3X3) = (X2 + Xx + X2)(X3)(Xx + X2)

— XxX2X3 + X1X1X3 + X1X2X3 + X2X2X3 + XxX2X3 + X2X2X3

(1.61)

There are two types of redundancies that can be used to simplify this

Подпись: Fig. 1.33. Boolean quantization of a typical fault tree.

equation. The redundancies apply because Boolean combinatorial logic is binary, variables in the logic can only be one or zero.

Thus the AND redundancy states that

A-A = A (1.62)

The OR redundancy states that

В + В = В (1.63)

and so also

B + BC^B (1.64)

The logic of each redundancy can be checked by considering the original definition of the two gates. For example, if an output only applies when both of two identical inputs apply, then it is the same as if there were only one input.

Подпись: Output = X,X2XS + XxX3 + X,X2X3 Подпись: X3X3 Подпись: XxX2X3 + X2X3

Applying the AND redundancy, Eq. (1.61) becomes

and then, removing the OR redundancies, the expression is reduced to:

Output = XxX3 + X2X3 (1.65)

This is now a nonredundant Boolean expression of the combinatorial

logic of the fault tree in Fig. 1.33. It can be used to derive a probability of the output event from the probabilities of the individual input events X±) -^2) and X3.

1.6.5.1.1 Probability calculus.+ The Boolean expression is transformed into a true probability expression using the following relationships:

(a) P(AB) = P(A)P(B) (1.66)

The probability of a number of events all occurring is a multiplication of the separate probabilities of each event.

(b) P(A + B) = P(A) + P(B) — P(A)P(B) (1.67)

The probability of one of several events occurring is the sum of the separate probabilities less the probability of their occurring together. If the probabili­ties of each event are small then the last term in this expression can be omitted.

Similar expressions apply for three or more variables.

Thus the probability of the final output in the fault tree of Fig. 1.33 is given by a transformation of the logic expression of Eq. (1.65) into a probability expression:

P(Output) = P(X,)P(X:i) + P(X2)P(X3) — P(X,)P(X:i)P(X2)P(X3) (1.68)

1.6.5.1.2 Repair time. It is not enough to know the probability of each event, as each failure may remain in operation for a different repair time. Thus an infrequent failure rate of a system may be associated with a long repair time, and this may be more significant than a high failure rate of a system associated with a very short repair time.

It is conservative to assume that nothing is repaired. It is indeed very pessimistic and unrealistic for a minor event that has a high probability of occurring. No really satisfactory solutions to the problem of mathe­matically representing the repair time have been found, although computer programs that assume constant failure rates and constant repair times do achieve very close approximation to the true results for small fault trees (200 inputs or less). Such programs are used in the aircraft industry where the probability of initiating faults in protection systems is well known and can be applied to reactor systems to advantage (16).

A constant failure rate assumes that the system is operating in the flat portion of the life reliability “bathtub” curve when the burn-in period has ended and before the wearout period becomes apparent (Fig. 1.34). This is a reasonably good assumption for systems that are tested throughout the burn-in peiiod and that are replaced before the wearout period commences; in particular, it is reasonable for certain electrical control equipment.

image072

Fig. 1.34. Life characteristic curve for mechanical and electrical equipment.

External Influences

The previous sections have outlined general disturbances to the reactor core. These disturbances may be ameliorated or aggravated by the control system or by human action.

2.6.1 Survey of Types

It is worth surveying possible initiators for the general disturbances so far considered, in particular, external initiators.

(a) Flow perturbations might arise from

(1) loss of electrical power to the plant or plant components result­ing in a loss of pumping power;

(2) pump mechanical failures;

(3) control malfunction.

(b) Reactivity perturbations might arise from

(1) the introduction of bubbles into the system;

(2) seismic deformations through structural movement;

(3) control malfunction;

(4) refueling accident.

(c) Thermal perturbations might arise from

(1) loss of feedwater supply;

(2) feedheater or turbine malfunctions resulting in a loss of heat removal capability;

(3) control malfunction in secondary and tertiary loops.

In each case a control malfunction is a possible cause of an accident, and as a result a controller error is treated in any safety assessment. The actual course of events depends critically on the mode of control used in any particular plant.

2.6.2 Control Modes

The control philosophy is shaped by certain restrictions which are set by plant material considerations and by the plant characteristics themselves.

The main requirements are: (a) a constant turbine stop-valve temperature, and (b) minimized temperature gradients in the vessel and in primary components. Whether or not these requirements are achievable depends on the time constants throughout the circuits of the system.

In a steam-cooled system which is a partly indirect cycle by virtue of the reheat cycle, load-following is possible if the feed supply-valve is administe­red correctly while the turbine stop-valve is varied. If the time constants and temperature feedback coefficients are suitable then this could be the control philosophy.

In a liquid-metal-cooled fast breeder the long delays in the intermediate circuit combined with positive void coefficients rule out load-following. A load-setting procedure is therefore a necessary control mode. This might take the following form: set the flow in the primary and secondary circuits; adjust the feed circuits; and adjust the reactivity in the core through control absorbers to meet the main control requirements listed above. The main problems are the difficulty in getting temperature signals from the core and the need to optimize control rod movement for small temperature changes.

Thus in the LMFBR control system, malfunctions might give rise to disturbances in primary, secondary, or feed flows, in reactivity, or possibly in a combination of all four.

In a given design a fault-tree analysis of the protective logic and the control system will be needed to decide on possible combinations of control operations that could give rise to adverse core effects. A faulty reduction of flows in the heat transfer loops following a signal of increased outlet temperatures would be an example of a gross control malfunction. The analysis of such possible malfunctions will need a combination of the analytical techniques discussed in Chapter 1.

One other possible control mode incident aggravation is worth mention. Noted above was the need to optimize control rod movement for small temperature changes. This optimization sometimes means the movement of a number of control rods in a staggered mode that makes it difficult to know what reactivity state the system is in at any given time. This ignorance of the reactivity state of the system hampered the diagnosis of the Fermi incident (see Section 4.6) which occurred during start-up.

Each control system must be treated as a special case for analysis.

Choice of Fast Reactor Coolants

The choice of a coolant is defined by a number of practical considerations. Primarily, excellent heat transport properties are required, but, in addition, the coolant should have little chemical activity and be compatible with the containment material so that corrosion is minimized. It should be stable and not be subject to decomposition even under irradiated conditions; its melting temperature should be low to avoid having to preheat the system to obtain a liquid coolant, but its boiling temperature should be high to avoid having to impose high pressures to suppress boiling. In addition its nuclear properties should be such that it is a poor moderator, and its indu­ced radioactivity build-up should be low to avoid having excessive shielding around the primary system. Added to all these requirements is the final one, that the coolant should be inexpensive; at least its cost should be a small fraction of the total cost of the plant.

Table 4.1 lists coolant properties for 15 potential liquid-metal coolants for fast reactors together with three evaluation parameters with which the effectiveness and suitability of a coolant candidate may be judged (2).

(a) The pumping power. This factor is a measure of the efficiency of the coolant. For systems with the same geometry, the same heat output, and the same temperature rise in the coolant channel, the pumping power varies
as

{10ЛІО2С2/

In this expression, /л is the viscosity in lb/ft-hr, £ is the density in lb/ft3, and cv is the specific heat in Btu/lb-°F. The pumping power is the product of the coolant volume flow and the channel pressure drop which is propor­tional to the friction factor. The friction factor is proportional to Rё02.

A low value of the pumping power is required in order to avoid an econo­mic penalty in heat transport. Table 4.1 shows that lithium has the lowest pumping power factor followed by zinc and gallium. Sodium ranks fourth in this assessment.

(b) Induced activity. The buildup in induced reactivity increases the amount of shielding required for the primary system and it therefore should be kept as low as possible. The specific activity in Ci/gm is given by

s = — Jr £ ‘W1 — exp(-O.6930/0,)] (4.1)

where is the atomic number of the z’th coolant isotope; N0 is Avogadro’s number (0.60248-1024); 9у is the neutron flux in the y’th energy interval (?z/cm2-sec); ац is the microscopic cross section for the z’th isotope and the y’th energy interval (cm2/nucleus); Aw is the coolant atomic weight (gm/gm — mole); тг is the coolant residence time within the neutron flux for one coolant cycle (sec); r0 is the cycle time for the coolant (sec); 6 is the irradia­tion time (sec); is the half-life for the z’th isotope (sec); and К is 3.7-1010 disintegrations/Ci-sec.

The exponential term accounts for the loss of activity due to the fast decay. Note too that the two cycle times rr and r0 depend on the heat transfer properties.

Table 4.1 once again shows that lithium is the most suitable coolant based on this assessment, followed by lead and an alloy of lead and bismuth. Sodium ranks seventh in the list although the addition of potassium brings it into fourth position.

(c) A temperature range ratio. In order to obtain some quantitative assessment of the working range of the coolant the following ratio of tem­peratures provides a useful measure

(Tb — Tm)/Tw (4.2)

Tb, Tm, and Tw are, respectively, the boiling, melting, and outlet absolute temperatures of the coolant (°R).

image168

image169

image170

Properties op Liquid Metals®

Potassium

Rubidium

Sodium

Tin

Zinc

Na(56%)-

K(44%)

Na(22%)-

K(78%)

Pb(44.5%)-

Bi(55.5%)

Sulfur

Phosphorus

19

37

11

50

30

16

15

39.100

85.48

22.997

118.70

65.38

30.082

35.557

208.2

32.066

31

44.6

84.4

51.4

421

428

47.4

46.3

625.5

102.5d

84.9е

0.41

0.415

0.55

2.736

6.192

0.47

0.43

2.88

680**

<1

0.0057c

0.0022^

0.0101

0.0347

0.0535

0.0071c

0.0078c

NA

0.00294

NA

48

60′

29

55.54

35.22

61

71

129.85

173d

NA

62

139

9

Neg.

Neg.

26і

45і

Neg.

310.2d

227.5e

 

146

102

208.1

449

787

66.2

12

257

246

111.5

1402

1270

1618

4118

1663

1518

1443

3038

832

536

0.182

0.0877

0.301

0.0639

0.1165

0.2485

0.209

0.035

0.248d

NA

21.2

13.2

37

19.0

33.2

16.4

15.05

8.05

0.0952

NA

25.5

11.0

48.7

26.1

43.92

NA

NA

NA

25 8»

9.06»

853

363

1718

1031

755.1

NA

NA

NA

121.2

254»

0.0035

0.00276і

0.0044

0.0095

0.022

0.0071

0.0060

0.0125

1771

<1

2.41

2.5

2.5

2.6

6.9

2.5

2.5

0.0

NA

NA

 

0.59

46.0

0.87

14.0

13.0

0.80

0.64

3.5

1.4*.*

3ft, i

4(3.7 MeV)

NA

<1

1

1

NA

NA

0.58і

NA

NA

12.4 hr

19 days

15 hr

112 days

None

See K,

Na See K,

Na None

None

None

0.32,

1.1

2.775,

0.39

None

NA

NA

None

None

None

1.51

0.0507

0.0234

1.368

0.0852

0.0169

0.0305

NA

NA

NA

0.0616

0.0637

 

S 3.66

S 390

SO.17

S 1.00

SO.13

S 0.60

S 0.80

See Pb, Bi

S 0.08

S 0.09

304 SS

304 SS

304 SS

Quartz

Graphite

304 SS

304 SS

Cr-Mo

steel

Graphite

NA

Slight1

Slight*

Slight*

SI. sol.

SI. sol.

Slight

Slight

SI. sol.

Reacts

Reacts

Slight1

Slight*

Slight*

Alloys

NA

Slight

Slight

SI. sol.

Reacts

Reacts

High

Moderate

High

None

None

High

High

High

Slight

Moderate

High

High

High

Slight as dust

Moderate

High

High

Moderate as dust

Slight

High

 

image171

A high value of this temperature ratio is desirable for a practical coolant, and Table 4.1 shows that tin, followed by gallium and an alloy of lead and bismuth head the merit table. This time lithium comes sixth while sodium comes eighth in the list. Other temperature factors could be used to assess working ranges but they give similar results.

Using these three evaluation parameters to choose a liquid-metal coolant would appear to lead to a choice of lithium followed by gallium.

However, lithium has a strong absorption cross section for fast neutrons. The main culprit is the eLi content and 7Li comprises 92.5% by weight of natural lithium, so the absorption can be reduced by enriching the lithium in its 7Li content. Lithium also has the disadvantage of having a low atomic number and it is therefore a strong moderator, three times as effective as sodium, which itself is a strong moderator. Strong moderation is undesirable because it degrades the spectrum and lowers the breeding ratio, and since breeding and neutron economy are most important to the success of the fast reactor, lithium cannot be used as a coolant. Gallium is far too expen­sive, even though the price could be expected to decrease if it were used in bulk.

Sodium is chosen as a coolant therefore, because it is a better-than — middle runner in all the assessment contests.

Spray Fires

If the sodium is sprayed out into an atmosphere that contains oxygen, then again the possibility of a fire is present. The sodium spray may arise from the failure of a primary sodium pipe under pressure or a similar cir­cumstance, although it is a little unlikely in an actual plant. Pipe leaks form­ing pools are more probable if a leak occurs.

When fine particles of sodium are sprayed into the air, the sodium may ignite at room temperature if it is in the form of a mist, although it may not ignite until the temperature is about 250°F if the sodium is in the form of droplets. The burning rate increases as the oxygen concentration is increased, up to 5%. It also increases if the moisture content of the atmosphere is increased, although there is no significant effect following an increase in the spraying pressure (55). Experiments have produced burning rates that are as rapid as the ejection rates themselves.

Heat from the spray fire is lost to the oxide particles, to the unburned sodium, to nitrogen in the air, and to the containment walls by radiation. Modeling of a spray fire must therefore take all these modes of heat transfer into account.

Due to the motion of the particle, the fire is less likely to be extinguished by oxide blanketing. Safety features that could be employed to protect against the consequences of spray fires include baffles to accumulate the spray volume thus reducing the heat transfer area and allowing the fire to be blanketed. A better safeguard is to provide inert gases only in proximity with sodium.

Hydrology

Precipitation. Average annual rainfall at the site is over 27 in. per year.

Drainage. Natural drainage of the site is provided by the land contours. The sub­terranean water travels toward the river at a velocity of 300 feet per year. The maximum temperature is 75°F with sufficient flow available to prevent exceeding the allowable temperature rise specified by the State.

Ground Water. Ground water in the region collects mostly in the weathered layer of the shale above the bedrock. Adequate ground water for sanitary supply and plant make­up is available within 50 feet below grade. Most wells in the region are drilled to the shale layer.

Geology and Seismology

Soil Profiles and Load Bearing Characteristics. Soil profiles for the site show alluvial soil and rock fill to a depth of 8 feet; Brassfield limestone to a depth of 30 feet; blue weathered shale and fossiliferous Richmond limestone to a depth of 50 feet; and bedrock over a depth of 50 feet. Allowable soil bearing is 6000 psf and rock bearing characteristics are 18,000 psf and 15,000 psf for Brassfield and Richmond strata, respectively. No under­ground cavities exist in the limestone.

Seismology. This is a Zone 1 site, as designated by the Uniform Building Code, based on the observation of three earthquakes of seismic intensities 6-8 on the Rossi-Forel scale in the period 1870-1958, causing minor damage to towns in the surrounding area.

Standards

Standards are also produced by the engineering societies and govern­mental institutions to provide limits for the design of various components.

For example, the American Society for Testing Materials (ASTM) provides for piping standards (4), and the United States of America Standards In­stitution (USASI) provides a vast number of everyday standards as well as those of use in the nuclear industry (5).

Sodium Void Coefficient or Density Coefficient in a Fast Reactor

This coefficient is very similar to the thermal density coefficient, but the emphasis is slightly different. The effects can be summarized in terms of the following.

(a) Absorption variation. The sodium removal reduces nonproductive absorption and relatively more neutrons are productively absorbed in the fuel. This is a positive effect.

(b) Leakage changes. As the diffusion length increases it leads to a greater leakage and gives a negative contribution to the coefficient.

(c) Moderation changes. There is less moderation and thus the fractional loss in energy per collision (the energy decrement) reduces and so the spectrum hardens. Thus the number of neutrons per fission (v) increases and this too gives a positive contribution (Table 1.4).

(d) Self-Shielding. Self-shielding decreases giving a positive effect.

TABLE 1.4

Comparative Absorption in Fast and Thermal Fluxes

Isotope

<t, (bams)

Fast

Thermal

23aPU

2.36

103

Fe

0.01

2.6

135Xe

3

3-Ю3

235 U

700

Thus the final sodium void coefficient is a matter of balance among these effects and the final value can be positive or negative. Because the effects are position dependent, the leakage being the dominating effect on the outer edges of the core and the moderation effect dominating at the core center, the sodium void coefficient is also very position dependent. Figure 1.13 shows the spatial variation of the sodium void coefficient and its components as a function of the core radius.

image023

Core radius

Fig. 1.13. The effect of sodium voiding as a function of core position (11).

System Modeling

Section 1.4 showed that reactivity changes arise through perturbations to Mission, and through changes in leakage. The reactivity variations are input into the calculational model through keff in the kinetic equations.

Such cross-section and leakage changes can arise from: (a) feedback effects from temperature changes, pressure changes, and structural move-

ment; and (b) external influences from control rod movement, the addition of poisons or moderator due to component failure, or core voiding in the sodium system. The magnitude of the reactivity effects from each cause is the concern of the physicist who evaluates them, using steady-state codes, as if the changes were a set of pseudo-steady states. These reactivity changes are then used on the presumption that the changes in reactivity occur more rapidly than the initiating mechanisms.

Thus the reactivity input is:

Л*(0=ЛО + МГі(0 (2.6)

where f(t) represents external influences and ST^t) symbolizes temperature and pressure changes which give rise to feedback effects. The latter are linked to relevant model equations which produce those temperatures and pressures.

image087

Fig. 2.11. The effect of various reactivity additions to a LMFBR operating at full power. The reactivity is added as a ramp terminated in 0.6 sec. Power variations are shown as a function of time.