The pyrolysis liquid was black and viscous and contained a significant proportion of charcoal of up to 15% by weight of the oil. This caused a "lumpy" texture in early samples. Atypical pyrolysis liquid analysis and a gas analysis is given in Table 5.3. The char was a coarse powder with particle sizes ranging from 40-50 microns to several mm, similar to the size and shape characteristics to the feed.
Table 5.2 Alten Typical Mass Balance
Basis: 100 kg d. a.f. biomass feed
INPUTS
|
kS
|
OUTPUTS
|
Ka
|
HHV. MJ/ko
|
% Enerav
|
Dry biomass
|
100.0
|
Charcoal
|
20.5
|
29.7
|
32
|
Moisture
|
2.0
|
Bio-oil
|
20.5
|
26.3
|
28
|
Pyrolysis air
|
39.0
|
Fuel gas
|
100.0
|
4.1
|
32
|
|
|
Losses
|
—
|
|
8
|
TOTAL
|
141.0
|
TOTAL
|
141.0
|
|
100
|
|
Table 5.3 Alten Typical Product Analyses
LIQUID GAS
Elemental Analysis {wet basis)
|
|
CO
|
27.6
|
% VO I.
|
C (% wt)
|
61.90
|
CO2
|
21.8
|
% vol.
|
H (% wt)
|
6.00
|
H2
|
4.7
|
% vol.
|
N (% wt)
|
1.05
|
O2
|
0.7
|
% vol.
|
S (% wt)
|
0.03
|
N2
|
38.2
|
% vol.
|
0 (by difference)
|
31.02
|
CH4
|
4.7
|
% vol.
|
H/C ratio
|
1.16
|
C2H4
|
0.4
|
% vol.
|
O/C ratio
|
0.18
|
C2H6
|
0.3
|
% vol.
|
Moisture (% wt)
|
14.60
|
Others (by difference)
|
1.6
|
% vol.
|
Ash (% wt)
|
1.50
|
Higher Heating Value
|
5 MJ/Nm3
|
Char content (% wt)
|
9.20
|
|
|
|
Viscosity, cp @ 70°C
|
55
|
SOLID
|
|
|
HHV, MJ/kg
|
26.3
|
Volatiles
|
|
15-20%
|
Specific gravity (15/4 °С)
|
1.195
|
Higher Heating Value
|
29.5 MJ/kg
|
|
|
Empirical formula
|
CH0.25°0.07
|
|