In situ recovery/leaching

Some orebodies lie in groundwater in porous unconsolidated material (such as gravel or sand) and may be accessed simply by dissolving the uranium and pumping it out — this is in situ leaching (ISL) mining (also known in North America as in situ recovery — ISR). It can be applied where the orebody’s aquifer is confined vertically and ideally horizontally. It is not licensed where potable water supplies may be threatened. Where appropriate it is certainly the mining method with least environmental impact.

I SL mining means that removal of the uranium minerals is accomplished without any major ground disturbance. Weakly acidified groundwater (or alkaline groundwater where the ground contains a lot of limestone such as in the USA) with a lot of oxygen in it is circulated through an enclosed underground aquifer, which holds the uranium ore in loose sands. The leaching solution dissolves the uranium before being pumped to a surface treatment plant where the uranium is recovered as a precipitate. Most US and Kazakh uranium production is by this method.

In Australian ISL mines the oxidant used is hydrogen peroxide and the complexing agent sulfuric acid to give a uranyl sulfate. Kazakh ISL mines generally do not employ an oxidant but use much higher acid concentrations in the circulating solutions. ISL mines in the USA use an alkali leach to give a uranyl carbonate due to the presence of significant quantities of acid-consuming minerals such as gypsum and limestone in the host aquifers. Any more than a few per cent carbonate minerals means that alkali leach must be used in preference to the more efficient acid leach.

In either the acid or alkali leaching method the fortified groundwater is pumped into the aquifer via a series of injection wells where it slowly migrates through the aquifer leaching the uranium bearing host sand on its way to strategically placed extraction wells where submersible pumps pump the liquid to the surface for processing.

Acid consumption in acid leach environments is variable depending on operating philosophy and geological conditions. In general, the acid consumption in Australian ISL mines is only a fraction of that used in a Kazakh mine (per kilogram of uranium produced). A general figure for Kazakh ISL production is up to 80 kg acid per kgU, though some mines are a bit lower. This is becoming a significant cost constraint there. Beverley in Australia is reported to be 3 kg/kgU.

For very small orebodies that are amenable to ISL mining, a central process plant may be distant from them so a satellite plant will be set up. This does no more than provide a facility to load the ion exchange (IX) resin/polymer so that it can be trucked to the central plant in a bulk trailer for stripping. Hence very small deposits can become viable, since apart from the wellfield, little capital expenditure is required at the mine and remote IX site.